在聚琥珀酰亚胺的基础上分别合成了含单羟基、双羟基、羧基、磺酸基四种基团的聚天冬氨酸(PASP)衍生物,采用静态失重法和电化学腐蚀法对其缓蚀性能进行了研究。试验结果表明,这几种聚天冬氨酸衍生物都是以抑制阳极为主的缓蚀剂,其中接枝双羟基的衍生物(DHPAP)的缓蚀效果最好,当加药量为100mg.L-1时缓蚀率达到92.8%,比聚天冬氨酸提高了50%以上。PASP、PASP-ASP(含羧基)在20天内的生物降解率在60%以上,具有优良的生物降解性,而PASP-SEA(含磺酸基)、HPAP(含单羟基)、DHPAP(含双羟基)属于可生物降解物质。
On the basis of polysuccinimide,four kinds of polyaspartic acid(PASP) derivatives respectively containing functional groups of single and double hydroxyl,carboxyl,sulfonic were synthesized.The methods of static weight-loss and electrochemical corrosion were employed to study the corrosion performance.The results show that those polyaspartic acid derivatives are anodic inhibitors,and grafted di-hydroxyl derivative has the best effect of corrosion inhibition,and the ratio of corrosion inhibition reached 92.8 % when the dosage was 100 mg·L-1,increased 50% more than polyaspartic acid.The order of inhibition efficiency to A3 steel of these five kinds of polyaspartic acid and its derivatives is PASP〈PASP-SEA〈PASP-ASP〈HPAP〈DHPAP.The biodegradation rates can reach up to 60% in 20 days.PASP-SEA,HPAP and DHPAP belong to biodegradable substance.
参考文献
[1] | 刘国华,奚旦立,李燕,陆柱.环保型无磷复合水处理剂的研制[J].腐蚀与防护,2003(11):480-482. |
[2] | 郭茹辉,贺正旺,张利辉,赵军平,田彩莉,李晓辉.无磷环保型水质稳定剂的研制及性能研究[J].河北化工,2009(01):25-27. |
[3] | 高玉华,吴运娟,刘振法,张利辉,闫美芳.聚天冬氨酸衍生物在水处理行业中的研究进展[J].河北工业科技,2008(03):181-185. |
[4] | 于晓英,黄君礼.绿色水处理剂-改性聚天冬氨酸的制备及其缓蚀性能研究[J].环境科学与管理,2008(04):113-116. |
[5] | 黄远星,雷中方,薛丹青.摇床试验法对聚天冬氨酸的生物降解性研究[J].工业水处理,2003(12):26-28,40. |
[6] | 王海平,海霞,李春梅,谷宁.聚天冬氨酸的研究及应用进展[J].河北师范大学学报(自然科学版),2008(04):517-522. |
[7] | 荆国林,赵海,王晓玉.可生物降解聚天冬氨酸阻垢剂性能研究[J].高分子材料科学与工程,2007(03):235-237,242. |
[8] | 霍宇凝,蔡张理,赵岩,陆柱.聚天冬氨酸及其与锌盐的复配物对碳钢缓蚀性能的影响[J].华东理工大学学报(自然科学版),2001(06):669-672. |
[9] | Morad MS .Some environmentally friendly formulations as inhibitors for mild steel corrosion in sulfuric acid solution[J].Journal of Applied Electrochemistry,2007(6):661-668. |
[10] | 黄远星,雷中方.聚天门冬氨酸类阻垢剂的生物降解性评定方法[J].复旦学报(自然科学版),2003(06):1053-1057. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%