综述了液相法(包括溶胶-凝胶法、蒸发诱导自组装法等)、电化学法(包括阳极氧化法、微弧氧化法等)、物理气相法(包括磁控溅射法、电子束蒸发法等)、化学气相法等制备多孔TiO<,2>薄膜的方法,介绍了相应的合成原理,指出不同方法制备的多孔TiO<,2>薄膜在表面形貌、孔径尺寸、取向和孔壁厚度等方面存在很大差异.通过对比不同制备方法的优缺点并结合工业化生产成本,提出了今后多孔TiO<,2>薄膜制备技术的发展方向,并展望了多孔TiO<,2>薄膜广阔的应用前景.
参考文献
| [1] | Dan HUANG,Guangsheng Luo,Liming Yang,Yujun Wang.SYNTHESIS OF MESOPOROUS TiO2 MATERIALS WITH HIGH SPECIFIC AREA USING INORGANIC ACIDS AS CATALYSTS[J].中国颗粒学报（英文版）,2005(03):176-180. |
| [2] | Everett D H .IUPAC manual of symbols and terminology[J].Pure and Applied Chemistry,1972,31:578. |
| [3] | 刘红霞,杨春.介孔TiO2的合成及光催化性能研究[J].南京师大学报（自然科学版）,2009(01):62-67. |
| [4] | 黄志峰,徐刚,徐雪青.多孔TiO2薄膜的制备及其表征[J].材料研究与应用,2008(04):520-522. |
| [5] | 张建,王慧,费书梅,宋洪昌.二氧化钛介孔材料的合成研究[J].材料导报,2006(z1):27-29. |
| [6] | Beck J S;Vartuli J C;Roth WJ et al.A new family of molecular-sieves prepared with liquid-crystal template[J].Journal of the American Chemical Society,1992,114:10834. |
| [7] | Janitabar-Darzi, S;Mahjoub, AR;Nilchi, A .Investigation of structural, optical and photocatalytic properties of mesoporous TiO2 thin film synthesized by sol-gel templating technique[J].Physica, E. Low-dimensional systems & nanostructures,2009(2):176-181. |
| [8] | Li Hui;Wang Jinshu;Li Hongyi et al.High thermal stability thick wall me.porous titania thin films[J].Materials Letters,2009,63:1583. |
| [9] | Bu S J;Jin Z G;Liu X X et al.Synthesis of TiO2 porous thin films by polyethylene glycol templating and chemistry of the process[J].Journal of the European Ceramic Society,2005,25:673. |
| [10] | Agarwala S;Ho G W .Synthesis and tuning of ordering and erystallinity of mesoporous titanium dioxide film[J].Materials Letters,2009,631:624. |
| [11] | Yong M J Q;Wong A S W;Ho G W .Mesophase ordering and macroscopic morphology structuring of mesoporous TiO2 film[J].Materials Chemistry and Physics,2009,116:563. |
| [12] | Xu Zhao;Manhong Liu;Yongfa Zhu .Fabrication of porous TiO_2 film via hydrothermal method and its photocatalytic performances[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(18):7127-7134. |
| [13] | 黄昀昉,吴季怀,魏月琳,郝三存,徐崧.纳米多孔TiO2薄膜的合成及其光电化学性能[J].矿物学报,2005(02):118-122. |
| [14] | Nicolau Y F .Solution deposition of thin solid compound films by a successive ionic-layer adsorption and reaction process[J].Applied Surface Science,1985,22-23:1061. |
| [15] | Patil U M;Gurav K V;Joo Oh-Shim et al.Synthesis of photosensitive nanograined TiO2 thin films by SILAR method[J].Journal of Alloys and Compounds,2009,478:711. |
| [16] | Mai Fu-Der;Lee Wen-Lian William;Chang Jia-Lin et al.Fabrication of porous TiO2 film on Ti foil by hydrothermal process and its photocatalytic efficiency and mechanisms with ethyl violet dye[J].Journal of Hazardous Materials B:Environmental Technologies,2010,177(1-3):864. |
| [17] | Sudhagar, P;Sathyamoorthy, R;Chandramohan, S .Influence of porous morphology on optical dispersion properties of template free mesoporous titanium dioxide (TiO2) films[J].Applied Surface Science,2008(7):1919-1928. |
| [18] | Lee, JJ .Application of inductively coupled plasma to CVD and PVD[J].Surface & Coatings Technology,2005(1/4):31-34. |
| [19] | 成晓玲,胡社军,匡同春,曾鹏,谢光荣,汝强.纳米二氧化钛薄膜制备研究进展[J].表面技术,2005(04):1-5,8. |
| [20] | Chen Zih-Yu;Hu Yi;Liu Tung-Cheng et al.Me.porous TiO2 thin films embedded with Au nanoparticles for the enhancement of the photocatalytic properties[J].THIN SOLID FILMS,2009,517:4998. |
| [21] | Ayumi Murakami;Toshiaki Yamaguchi;Shin-ichi Hirano;Koichi Kikuta .Synthesis of porous titania thin films using carbonatation reaction and its hydrophilic property[J].Thin Solid Films,2008(12):3888-3892. |
| [22] | Lu, C;Chen, Z .High-temperature resistive hydrogen sensor based on thin nanoporous rutile TiO2 film on anodic aluminum oxide[J].Sensors and Actuators, B. Chemical,2009(1):109-115. |
| [23] | Chen Chung-Shou;Pan Fu-Ming .Electrocatalytic activity of Pt nanoparticles deposited on porous TiO2 supports toward methanol oxidation[J].Applied Catalysis B:Environmental,2009,91:663. |
| [24] | Masayuki Okuya;Katsuyuki Shiozaki;Nobuyuki Horikawa et al.Porous TiO2 thin films prepared by spray pyrolysis deposition(SPD) technique and their application to UV sensors[J].Solid-State Ionicis,2004,172:527. |
| [25] | Masayuki Okuya;Koji Nakade;Shoji Kaneko .Porous TiO2 thin films synthesized by a spray pyrolysis deposition (SPD) technique and their application to dye-sensitized solar cells[J].Solar Energy Materials & Solar Cells,2002,70:425. |
| [26] | 陶杰,王炜,陶海军,王玲.电解液对纯钛表面TiO2多孔膜形态及晶型的影响[J].中国有色金属学报,2005(04):578-583. |
| [27] | Grzegorz D. Sulka;Joanna Kapusta-Kolodziej;Agnieszka Brzozka;Marian Jaskula .Fabrication of nanoporous TiO_2 by electrochemical anodization[J].Electrochimica Acta,2010(14):4359-4367. |
| [28] | Bayati M R;Wu Hanhua;Lu Xianyi et al.The effects of cathodic and anodic voltages on the characteristics of porous nanocrystalline titania coatings fabricated by microarc oxidation[J].Materials Letters,2005,59:370. |
| [29] | Bayati M R;Moshfeghc A Z;Golestani-Fard F .In situ growth of vanadia-titania nano/micro-porous layers with enhanced photocatalytic performance by micro-arc oxidation[J].Electrochimica Acta,2010,55:3093. |
| [30] | Yao ZQ;Ivanisenko Y;Diemant T;Caron A;Chuvilin A;Jiang JZ;Valiev RZ;Qi M;Fecht HJ .Synthesis and properties of hydroxyapatite-containing porous titania coating on ultrafine-grained titanium by micro-arc oxidation.[J].Acta biomaterialia,2010(7):2816-2825. |
| [31] | Katrin Wessels;Miyuki Maekawa;Jiri Rathousky .Highly porous TiO2 films from anodically deposited titanate hybrids and their photoelectrochemical and photocatalytic activity[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2008(1/3):55-61. |
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