作为新型非线性光学材料，钙－稀土硼酸盐晶体Ｃａ４ＲＯ（ＢＯ３）３（Ｒ－Ｌａ３＋、Ｎｄ３＋、Ｓｍ３＋Ｇｄ３＋Ｙ３＋Ｅｒ３＋、Ｔｂ３＋、Ｌｕ３+）近来引起了广泛的重视．该系列晶体属非中心对称的单斜晶系，空间群Ｃｍ．本文综述了上述晶体的结构和生长研究的进展。总结了晶体的线性光学／非线性光学性能以及掺杂晶体的激光自倍频性能，指出这些晶体在非线性光学领域潜在的应用前景．
The isostructural calcium rare-earth oxyborates Ca4RO(BO3)3(R---La3+, Nd3+, Sm3+, Gd3+, Y3+, Er3+, Tb3+, Lu3+)
as nonlinear optical materials have attracted great attentions recently. They belong to the monoclinic crystallographic system with space group Cm. The progress on the research of their structures and crystal growth was reviewed, and their linear/nonlinear optical
properties and self-frequency doubling properties were also summarized in detail. It was suggested that these crystals possess potential
applications in frequency conversion.
参考文献
| [1] | Khamaganova T N, Trunov V K, Dzhurinskii B F. Russ. J. Inorg. Chem., 1991, 36: 484--485. [2] Norrestem R, Nygren M, Bovin J O. Chem. Mater., 1992, 4: 737--743. [3] Ilyukhin A B, Dzhurinskii B F. Russ. J. Inorg. Chem., 1993, 38: 847--850. [4] Aka G, et al. Eur. J. Solid State Inorg. Chem., 1996, 33: 727--736. [5] Iwai M, et al. Jpn. J. Appl. Phys., 1997, 36: L276--L279. [6] Chai B H T. Proceedings of International Symposium on Laser and Nonlinear Optical Materials, Singapore, 1997. 34--37. [7] Aka G, et al. European patent extension 96904152. 4-2205 (February 16, 1996). [8] Kobayashi T, et al. J. Japanese Association for Crystal Growth, 1997, 24: 213. [9] Furuya H, et al. J. Japanese Association for Crystal Growth, 1998, 25: 193--199. [10] Ye Q, Chai B H T. J. Crystal Growth, 1999, 197: 228--235. [11] 宫波等. 人工晶体学报， 1999, 28: 31--36. [12] van Schaik W, et al. J. Luminescence, 1995, 63: 103--115. [13] Aka G, et al. J. Opt. Soc. Am. B, 1997, 14 (9): 2238--2247. [14] Kobayashi T, et al. Proceedings of International Symposium on Laser and Nonlinear Optical Materials, Singapore, 1997. 317--319. [15] 张克从等主编. 晶体生长科学与技术(上册). 北京：科学出版社， 1997. 506--507. [16] Yoshimura M, et al. SPIE, Beijing, 1998, 3556: 210--213. [17] Jang W K, et al. CFG4, CLEO’98, 1998. 270. [18] 陈纲，廖理几编著. 晶体物理学基础. 北京：科学出版社， 1992. 413--416. [19] Mougel F, et al. Optical Materials, 1997, 8: 161--173. [20] Mougel F, et al. Appl. Phys. B, 1998, 67: 533--535. [21] 孟宪林等. 中国激光， 1998, 25: 876. [22] 孟宪林等. 中国激光， 1999, 26: 108. [23] Zhang H J, et al. Optics Communications, 1999, 160: 273--276. [24] Zhang H J, et al. J. Crystal Growth, 1999, 200: 335--338. [25] Wallace J. Laser Focus World, 1999, 35 (2): 24--26. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%