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采用共沉淀法制备了不同Zn2+掺杂量的CO1-xZnxFe2O4,研究了Zn2+掺杂量对其结构和磁性的影响.X射线衍射测试表明CO1-xZnxFe2O4成相良好,结晶随烧结温度增加而愈加完善.经400C热处理2h的Co0.7Zn0.3Fe2O4晶粒尺寸由谢乐公式计算为8.57nm.利用振动样品磁强计研究其静态磁性,结果表明,Zn2-掺杂量对CO1-xZnxFe2O4磁性有显著影响,Zn2+含量越高矫顽力越低,同时饱和磁化强度越大,当x=0.3时,矫顽力仅为1352.82A/m,磁化强度为42A·m2/kg,实现了CoFe2O4从硬磁性到软磁性的转变,可作为潜在的高频软磁材料.

参考文献

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