欢迎登录材料期刊网

材料期刊网

高级检索

制备了Ti、Al含量不同的热浸镀锌层,利用扫描电子显微镜(SEM)和能谱仪(EDS)观察分析了镀层的组织结构.结果表明:Ti能有效抑制镀层中ζ相的生长,降低合金相层的厚度.60 s浸镀,添加0.04% Ti时消除了镀层中ζ相分层现象;添加0.07% Ti时在ζ/η相界生成细小颗粒状T相;240 s浸镀,在ζ/η界面及η相中生成了颗粒状T相,甚至形成连续分布的T相小岛.锌浴中同时添加Ti和Al对Fe-Zn合金相生长的抑制作用加剧,短时间浸镀时就促使含铝T相在η相中生成.

参考文献

[1] 张清辉,陈冷,毛卫民,段外琴,师绍广.钢带热镀锌技术研究进展[J].金属热处理,2009(12):78-82.
[2] Pistofidis N;Vourlias G;Pavlidou E;Stergioudis G .Effect of Ti, Ni and Bi addition to the corrosion resistance of Zn hot-dip galvanized coatings[J].Journal of optoelectronics and advanced materials,2007(6):1653-1659.
[3] Vourlias G;Pistofidis N;Stergioudis G;Pavlidou E;Tsipas D .Influence of alloying elements on the structure and corrosion resistance of galvanized coatings[J].Physica Status Solidi, A. Applied Research,2004(7):1518-1527.
[4] Amadeh A;Pahlevani B;Heshmati Manesh S .Effects of rare earth metal addition on surface morphology and corrosion resistance of hot-dipped zinc coatings[J].Corrosion Science,2002,44(10):2321-2331.
[5] 闫瑞华,张克,孙虎元,孙立娟,刘增文.添加钛元素对热浸镀锌层性能的影响[J].海洋科学,2008(11):20-23.
[6] 许乔瑜,桂艳,卢锦堂,孔纲,车淳山.热浸Zn-Ti合金镀层的显微组织与耐蚀性能[J].华南理工大学学报(自然科学版),2008(07):82-86.
[7] 魏世丞,朱晓飞,魏绪钧.铝和钛对热镀锌层的影响[J].材料保护,2003(09):28-30.
[8] 黄国雄,王胜民,何明奕,赵晓军,苑振涛.热浸镀Zn-Ti及Zn-Ti-Al合金层的耐蚀性能[J].材料保护,2010(12):11-13.
[9] Nakano J;Malakhov DV;Yamaguchi S;Purdy GR .A full thermodynamic optimization of the Zn-Fe-Al system within the 420-500 degrees C temperature range[J].Calphad: Computer Coupling of Phase Diagrams and Thermochemistry,2007(1):125-140.
[10] Marder AR. .The metallurgy of zinc-coated steel [Review][J].Progress in materials science,2000(3):191-271.
[11] G.K. Mandal;D. Mandal;S.K. Das .Microstructural study of galvanized coatings formed in pure as well as commercial grade zinc baths[J].Transactions of the Indian Institute of Metals,2009(1):35-40.
[12] Reumont G;Tissier J C;Dauphin J Y et al.Morphology,structure and formation conditions of drosses in hot dip galvanizing nickel-added baths[J].Memoires et Etudes Scientifiques Revue de Metallurgie,1989,86(12):799-809.
[13] G. Reumont;T. Gloriant;P. Perrot .The zinc-rich corner of the Fe-Zn-Ni-Ti quaternary system at 450 °C[J].Journal of Materials Science Letters,1997(1):62-65.
[14] V. Raghavan .Fe-Ti-Zn (Iron-Titanium-Zinc)[J].Journal of Phase Equilibria,2002(2):182-183.
[15] Tang NY.;Toguri JM.;Su XP. .Experimental study and thermodynamic assessment of the Zn-Fe-Ni system[J].Calphad: Computer Coupling of Phase Diagrams and Thermochemistry,2001(2):267-277.
[16] Nai-Yong Tang;Xuping Su;Xuebin Yu .The Zn-rich corner of the Zn-Fe-Co system at 450℃[J].Zeitschrift fur Metallkunde,2003(2):116-121.
[17] Xianhui Tang;Fucheng Yin;Xinming Wang .The 450 deg C Isothermal Section of the Zn-Fe-Ti System[J].Journal of Phase Equilibria and Diffusion,2007(4):355-361.
[18] G. Reumont;T. Gloriant;P. Perrot .Experimental influence of kinetics on galvanized coatings when saturating a zinc bath with alloying elements[J].Journal of Materials Science Letters,1996(5):445-449.
[19] Nakano J;Malakhov DV;Purdy GR .A crystallographically consistent optimization of the Zn-Fe system[J].Calphad: Computer Coupling of Phase Diagrams and Thermochemistry,2005(4):276-288.
[20] J. D. Culcasi;P. R. Sere;C. I. Elsner;A. R. Di Sarli .Control of the growth of zinc-iron phases in the hot-dip galvanizing process[J].Surface & Coatings Technology,1999(1):21-23.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%