通过浮选实验和红外光谱测定, 考查了铁闪锌矿在无捕收剂或以乙黄药为捕收剂时的浮选行为.结果表明: 铁闪锌矿在酸性条件下, 可实现无捕收剂浮选, 硫酸铜的活化效果不明显; 在乙黄药体系下, 铁闪锌矿只能在酸性条件下可浮, 表面生成产物主要为乙黄原酸锌; 但有硫酸铜存在时, 铁闪锌矿可浮性得到大大改善, 当硫酸铜用量达到一定程度, 在整个pH值范围内铁闪锌矿均有较好的可浮性, 铁闪锌矿表面生成物为CuEX.
参考文献
[1] | Girczys J;Laskowski J.Mechanism of flotation of unactivated sphalerite with xanthates[J].Transactions of the Institution of Mining and Metallurgy,1972(81):118-127. |
[2] | Mukherjee A D;Sen P K.Floatability of sphalerite in relation to its iron content[J].Journal of Mines,Metals and Fuels,1976(10):327-334. |
[3] | Finkelstein N P;Allison S A.The chemistry of activation, deactivation and depression in the flotation of zinc sulfide: a review[M].Gandin Memorial Volume Flotation; A M,1976:414. |
[4] | 松全元.二氧化硫对闪锌矿可浮性影响的研究[J].国外金属矿选矿,1983(01):51-58. |
[5] | SONG Quan·yuan.The study for effect of sulphur dioxide on sphalerite flotation floatability[J].Journal of International Metal Mineral Processing,1983(01):51-58. |
[6] | Finkelstein N P .The activation of sulphide minerals for flotation:a review[J].International Journal of Mineral Processing,1997,52:120-181. |
[7] | Finkelstein N P .Addendum to the activation of sulphide minerals for flotation:a review[J].International Journal of Mineral Processing,1999,55:283-286. |
[8] | Trahar W J;Senior G D;Heyes G W et al.The activation of sphalerite by lead-a flotation perspective[J].International Journal of Mineral Processing,1997,49:121-148. |
[9] | Mory M S;Grano S R;Ralston J et al.The electrochemistry of PbⅡ activated sphalerite in relation to flotation[J].Minerals Engineering,2001,14(09):1009-1017. |
[10] | Fereshteh Rashchi;Caroline Sui;James A. Finch .Sphalerite activation and surface Pb ion concentration[J].International Journal of Mineral Processing,2002(1/4):43-58. |
[11] | 伊云 R H .在酸性溶液中用铜离子活化闪锌矿的电化学研究[J].国外金属矿选矿,1997,6:13-19. |
[12] | Yiyun R H .The electrochemical study of Cu ion activation sphalerite in acidity solution[J].Journal of International Metal Mineral Processing,1997,6:13-19. |
[13] | Andrea R G;Angela G L;Kathryn E P et al.The mechanism of copper activation of sphalerite[J].Applied Surface Science,1999,137:207-223. |
[14] | 分析化学手册[M].北京:化学工业出版社,1997 |
[15] | Analytical Chemistry Handbook(Ⅱ)[M].北京:化学工业出版社,1997 |
[16] | Mielczarski J .The role of impurities of sphalerite in the adsorption of ethyl xanthate and its flotation[J].International Journal of Mineral Processing,1986,16:179-194. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%