聚合物太阳能电池由于质量轻、成本低、柔韧性好及制备工艺简便等优点而具有巨大的潜在应用价值,是太阳能电池发展的新方向.但是聚合物太阳能电池的能量转换效率较低,达不到商业化应用的要求,如何提高电池效率仍是目前研究的重点.聚合物材料和光敏层的形貌是影响太阳能电池性能的两大要素,从机理方面分析了限制太阳能电池效率的一些因素,介绍了聚合物材料的新进展,探讨了聚合物材料设计的原则及方法,着重探讨了形貌对太阳能电池性能的影响以及改进形貌的方法及其理论基础,并展望了聚合物太阳能电池未来的发展趋势.
参考文献
[1] | Heindel T;Schneider C;Lermer M et al.Electrically driven quantum dot-micropillar single photon source with 34% overall efficiency[J].Applied Physics Letters,2010,96:011107. |
[2] | Geisz J F;Friedman D J;Ward J S et al.40.8% efficient inverted triple-junction solar cell with two independently metamorphic junctions[J].Applied Physics Letters,2008,93:123505. |
[3] | R. R. King;D. C. Law;K. M. Edmondson;C. M. Fetzer;G. S. Kinsey;H. Yoon;R. A. Sherif;N. H. Karam .40percent efficient metamorphic GaInP/GaInAs/Ge multijunction solar cells[J].Applied physics letters,2007(18):183516-1-183516-3-0. |
[4] | Sean E. Shaheen;Rachel Radspinner;Nasser Peyghambarian;Ghassan E. Jabbour .Fabrication of bulk heterojunction plastic solar cells by screen printing[J].Applied physics letters,2001(18):2996-2998. |
[5] | Hoth, CN;Choulis, SA;Schilinsky, P;Brabec, CJ .High photovoltaic performance of inkjet printed polymer: Fullerene blends[J].Advanced Materials,2007(22):3973-3978. |
[6] | Aernouts T;Aleksandrov T;Girotto C et al.Polymer based organic solar cells using ink-jet printed active layers[J].Applied Physics Letters,2008,92:033306. |
[7] | Vak DJ;Kim SS;Jo J;Oh SH;Na SI;Kim JW;Kim DY .Fabrication of organic bulk heterojunction solar cells by a spray deposition method for low-cost power generation[J].Applied physics letters,2007(8):81102-1-81102-3-0. |
[8] | Krebs, Frederik C. .Roll-to-roll fabrication of monolithic large-area polymer solar cells free from indium-tin-oxide[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2009(9):1636-1641. |
[9] | Krebs F C;Gevorgyan S A;Alstrup J .A roll-to-roll process to flexible polymer solar cells;Model studies,manufacture and operational stability studies[J].Journal of Materials Chemistry,2009,19:5442. |
[10] | Markvart T;Castafier L.Solar cells:Materials,manufacture and operation[M].Holland:Elsevier,2005 |
[11] | 施敏敏,陈红征,吴刚,汪茫.有机太阳电池面临的机遇、问题和对策[J].电源技术,2008(10):709-712,720. |
[12] | Chen H Y;Hou J H;Zhang S Q et al.Polymer solar cells with enhanced open-circuit voltage and efficiency[J].Nature Photonics,2009,3:649. |
[13] | Blom PWM;Mihailetchi VD;Koster LJA;Markov DE .Device physics of polymer : fullerene bulk heterojunction solar cells[J].Advanced Materials,2007(12):1551-1566. |
[14] | 张正华;李陵岚;叶楚平.有机太阳能电池与塑料太阳能电池[M].北京:化学工业出版社,2006 |
[15] | Bundgaard E;Krebs FC .Low band gap polymers for organic photovoltaics[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(11):954-985. |
[16] | D. Mühlbacher;M. Scharber;M. Morana;Z. Zhu;D. Waller;R. Gaudiana;C. Brabec .High Photovoltaic Performance of a Low-Bandgap Polymer[J].Advanced Materials,2006(21):2884-2889. |
[17] | Park, SH;Roy, A;Beaupre, S;Cho, S;Coates, N;Moon, JS;Moses, D;Leclerc, M;Lee, K;Heeger, AJ .Bulk heterojunction solar cells with internal quantum efficiency approaching 100%[J].Nature photonics,2009(5):297-303. |
[18] | O.Inganas;M.Svensson;F.Zhang;A.Gadisa;X.Wang;M.R.Andersson;N.K.Persson .Low bandgap alternating polyfluorene copolymers in plastic photodiodes and solar cells[J].Applied physics, A. Materials science & processing,2004(1):31-35. |
[19] | WAI-YEUNG WONG;XING-ZHU WANG;ZE HE .Metallated conjugated polymers as a new avenue towards high-efficiency polymer solar cells[J].Nature materials,2007(7):521-527. |
[20] | Koster L J A;Mihailetchi V D;Blom P W M .Ultimate efficiency of polymer/fullerene bulk heteroj unction solar cells[J].Applied Physics Letters,2006,88:093511. |
[21] | Scharber, MC;Wuhlbacher, D;Koppe, M;Denk, P;Waldauf, C;Heeger, AJ;Brabec, CL .Design rules for donors in bulk-heterojunction solar cells - Towards 10 % energy-conversion efficiency[J].Advanced Materials,2006(6):789-795. |
[22] | Christoph J. Brabec;Christoph Winder;N. Serdar Sariciftci;Jan C. Hummelen;Anantharaman Dhanabalan;Paul A. van Hal;Rene A. J. Janssen .A Low-Bandgap Semiconducting Polymer for Photovoltaic Devices and Infrared Emitting Diodes[J].Advanced materials for optics and electronics,2002(10):709-712. |
[23] | Liang, YY;Feng, DQ;Wu, Y;Tsai, ST;Li, G;Ray, C;Yu, LP .Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties[J].Journal of the American Chemical Society,2009(22):7792-7799. |
[24] | Morvillo P;Bobeico E .Tuning the LUMO level of the acceptor to increase the open-circuit voltage of polymer-fullerene solar cells: A quantum chemical study[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(10):1192-1198. |
[25] | Youjun He;Hsiang-Yu Chen;Jianhui Hou;Yongfang Li .Indene-C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells[J].Journal of the American Chemical Society,2010(4):1377-1382. |
[26] | Kim Y;Cook S;Tuladhar SM;Choulis SA;Nelson J;Durrant JR;Bradley DDC;Giles M;Mcculloch I;Ha CS .A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene: fullerene solar cells[J].Nature materials,2006(3):197-203. |
[27] | Dennler G;Scharber M C;Brabec C J .Polymer-fullerene bulk-heterojunction solar cells[J].Advanced Materials,2009,21(13):1323. |
[28] | Jespersen KG;Zhang FL;Gadisa A;Sundstrom V;Yartsev A;Inganas O .Charge formation and transport in bulk-heterojunction solar cells based on alternating polyfluorene copolymers blended with fullerenes[J].Organic electronics,2006(4):235-242. |
[29] | Andersson L M;Ingan(a)s O .Acceptor influence on hole mobility in fullerene blends with alternating copolymers of fluorene[J].Applied Physics Letters,2006,88:082103. |
[30] | GANG LI;VISHAL SHROTRIYA;JINSONG HUANG;VAN YAO;TOM MORIARTY .High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends[J].Nature materials,2005(11):864-868. |
[31] | Sean E. Shaheen;Christoph J. Brabec;N. Serdar Sariciftci;Franz Padinger;Thomas Fromherz;Jan C. Hummelen .2.5% efficient organic plastic solar cells[J].Applied physics letters,2001(6):841-843. |
[32] | Joachim A. Renz;Pavel A. Troshin;Gerhard Gobsch;V. F. Razumov;Harald Hoppe .Fullerene solubility–current density relationship in polymer solar cells[J].physica status solidi(RRL): rapid research letterse,2008(6):263-265. |
[33] | Yang XN;Loos J;Veenstra SC;Verhees WJH;Wienk MM;Kroon JM;Michels MAJ;Janssen RAJ .Nanoscale morphology of high-performance polymer solar cells[J].Nano letters,2005(4):579-583. |
[34] | Kim Y;Choulis SA;Nelson J;Bradley DDC;Cook S;Durrant JR .Device annealing effect in organic solar cells with blends of regioregular poly(3-hexylthiophene) and soluble fullerene[J].Applied physics letters,2005(6):3502-1-3502-3-0. |
[35] | Wanli Ma;Cuiying Yang;Xiong Gong;Kwanghee Lee;Alan J. Heeger .Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology[J].Advanced functional materials,2005(10):1617-1622. |
[36] | Li G;Yao Y;Yang H;Shrotriya V;Yang G;Yang Y ."Solvent annealing" effect in polymer solar cells based on poly(3-hexylthiophene) and methanofullerenes[J].Advanced functional materials,2007(10):1636-1644. |
[37] | Mihailetchi V D;Xie H X et al.Origin of the enhanced performance in poly (3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester solar cells upon slow drying of the active layer[J].Applied Physics Letters,2006,89:012107. |
[38] | Jo J;Na S I;Kim S S et al.Three-dimensional bulk heterojunction morphology for achieving high internal quantum fficiency in polymer solar cells[J].Advanced Functional Materials,2009,19(15):2398. |
[39] | Jong Hwan Park;Jong Soo Kim;Ji Hwang Lee .Effect of Annealing Solvent Solubility on the Performance of Poly(3-hexylthiophene)/ Methanofullerene Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(40):17579-17584. |
[40] | Peet J;Soci C;Coffin R C et al.Method for increasing the photoconductive response in conjugated polymer/fullerene composites[J].Applied Physics Letters,2006,89:252105. |
[41] | J.PEET;J.Y.KIM;N.E.COATES .Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols[J].Nature materials,2007(7):497-500. |
[42] | Yao Y;Hou J H;Xu Z et al.Effects of solvent mixtures on the nanoscale phase separation in polymer solar cells[J].Advanced Functional Materials,2008,18(16):1783. |
[43] | G. D. Sharma;P. Suresh;S. S. Sharma .Effect of Solvent and Subsequent Thermal Annealing on the Performance of Phenylenevinylene Copolymer:PCBM Solar Cells[J].ACS applied materials & interfaces,2010(2):504-510. |
[44] | Berson, S;De Bettignies, R;Bailly, S;Guillerez, S .Poly (3-hexylthiophene) fibers for photovoltaic applications[J].Advanced Functional Materials,2007(8):1377-1384. |
[45] | IoanBotiz;SethB.Darling .Self-AssemblyofPoly(3-hexylthiophene)-block-polylactideBlockCopolymerandSubsequentIncorporationofElectronAcceptorMaterial[J].Macromolecules,2009(21):8211-8217. |
[46] | Svanstrom C M B;Rysz J;Bernasik A et al.Device performance of APFO3/PCBM solar cells with controlled mor-phology[J].Advanced Materials,2009,21(43):4398. |
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