主要研究了在尼龙6/粘土(NYC)与聚乙烯醇(PVA)共混复合物中尼龙6的晶型转变.在差示扫描量热(DSC)和X射线衍射的表征中发现,当PVA的含量小于16.7%时,PVA的α晶型消失.随着NYC/PVA体系中NYC含量的增加,原来存在于NYC中尼龙6主要的γ晶型逐渐转变为α晶型;当PVA的含量等于或大于50%时,在NYC/PVA体系中只存在α晶型的尼龙6结晶.用扫描电镜(SEM)进一步分析经离子束刻蚀的NYC/PVA样品发现,随PVA含量的增加所产生尼龙6晶型的转变现象,主要是由粘土迁移行为造成的.
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