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实验研究了CaO及与CO对N2O、NO的催化还原作用。结果表明CaO/CO对N2O的作用表现在可以降低N2O的初始分解温度和提高N2O的转化率;只有在CO的共同作用下CaO可以提高NO的转化率。以此为基础,分析了不同规模的流化床燃烧不同挥发份含量的煤时加入CaO后影响N2O/NO排放的不同机理

A laboratory study of reduction of N2O and NO over CaO under fluidizedbed combustion (FBC) conditions is reported. The initial decompositiontemperature of N2O is reduced to 1050 K from 1150 K in the presence of CaO,while the temperature is 950 K together with CO. The conversions ofN2O are enhanced from 10% to 32% and 70% respectively at 1123 K. However,CaO has only a small effect on the reduction of NO. The results from thepresent work and from the literatures are used to discuss how limestoneaddition influences the emissions of N2O/NO in FBC. The results indicatethat mechanisms of CaO/CO on N2O/NO are relative to the volatile contentof the fuel and the scale of the fluidized bed

参考文献

[1] L E,Andersson S.Emission of Nitrous Oxidefrom Fluidized Bed Boilers[A].ASME,1989:49-55.
[2] 冯波;袁建伟;林志杰 等.流化床燃烧工况下N2O多相分解的机理研究[J].工程热物理学报,1995,16(01):111-114.
[3] A N Lawrence A D .The Effect of Solid CaO on the Productionof NOx and N20 in Fluidized Bed Combustors: Studies Using Pyridine asa Prototypical Nitrogenous Fuel[J].Combustion and Flame,1996,105:511-527.
[4] P F B;Johansen K D.Limestone Catalyzed Reduction of NO andN2O under Fluidized Bed Combustion Conditions[A].ASME,1993:779-787.
[5] J E;Jersen A.Decomposition and Reduction of N2O overLimestone under FBC Conditions[A].ASME,1997:953-966.
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