TiO2(锐钛矿)的禁带宽度限制了其光诱导特性的广泛应用,非金属元素掺杂为TiO2在可见光辐射环境下的应用提供了新的机会.详细介绍了非金属元素(N、C、S、F)掺杂TiO2的制备方法和可见光催化活性研究的最新进展,讨论了制备工艺与掺杂TiO2可见光催化活性的关系,深入分析了非金属元素对TiO2可见光催化活性的诱导机理.制备工艺显著影响了掺杂元素的化学态和含量,从而决定了掺杂TiO2带隙中局域态的特征.带隙中局域态特征正是影响掺杂TiO2可见光催化活性的关键因素.文章也对未来的研究方向进行了展望.
参考文献
[1] | Carp O;Huisman C L;Reller A .[J].Progress in Solid State Chemistry,2004,32:33-177. |
[2] | Fujishima A;Rao T N;Tryk D A.[J].Journal of Photochemistry & Photobiology C:Photochemistry Reviews,2000(01):1-21. |
[3] | Fujishima A;Honda K .[J].Nature,1972,238:37-38. |
[4] | Asahi R;Morikawa T;Ohwaki T et al.[J].Science,2001,293(5528):269-271. |
[5] | Meng Ni;Michael K.H. Leung;Dennis Y.C. Leung;K. Sumathy .A review and recent developments in photocatalytic water-splitting using TiO_2 for hydrogen production[J].Renewable & Sustainable Energy Reviews,2007(3):401-425. |
[6] | Wang R;Hashimoto K;Fujishima A et al.[J].Nature,1997,388:431-432. |
[7] | Gandhe, AR;Naik, SP;Fernandes, JB .Selective synthesis of N-doped mesoporous TiO2 phases having enhanced photocatalytic activity[J].Microporous and Mesoporous Materials,2005(2):103-109. |
[8] | Davydov L;Reddy E P;France P et al.[J].Journal of Catalysis,2001,203:157-167. |
[9] | Klosek S;Raftry D .[J].Journal of Physical Chemistry B,2001,105:2815-2819. |
[10] | Zhou Jinkai;Takeuchi M;Zhao X S et al.[J].Catalysis Letters,2006,106(1-2):67-70. |
[11] | Khan S U M;Al-Shahry M;Ingler Jr W B .[J].Science,2002,297:2243-2245. |
[12] | Lindgren T;Lu J;Hoel A;Granqvist CG;Torres GR;Lindquist SE .Photo electrochemical study of sputtered nitrogen-doped titanium dioxide thin films in aqueous electrolyte[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(1/4):145-157. |
[13] | Sato S;Nakamura R;Abe S .Visible-light sensitization of TiO2 photocatalysts by wet-method N doping[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):131-137. |
[14] | Sakthivel S;Kisch H.[J].ChemPhysChem:A European Journal of Chemical Physics and Physical Chemistry,2003(04):487-490. |
[15] | Ihara T;Miyoshi M;Iriyama Y et al.[J].Applied Catalysis B:Environmental,2003,42:403-409. |
[16] | Wang Zhengpeng;Cai Weimin;Hong Xiaoting et al.[J].Applied Catalysis B:Environmental,2005,57:223-231. |
[17] | Liu Y;Chen X;Li J et al.[J].Chemosphere,2005,61:11-18. |
[18] | Burda C;Lou Y;Chen X et al.[J].Nano Letters,2003,3:1049-1051. |
[19] | Chen XB;Lou YB;Samia ACS;Burda C;Gole JL .Formation of oxynitride as the photocatalytic enhancing site in nitrogen-doped titania nanocatalysts: Comparison to a commercial nanopowder[J].Advanced functional materials,2005(1):41-49. |
[20] | Prokes SM;Gole JL;Chen XB;Burda C;Carlos WE .Defect-related optical behavior in surface-modified TiO2 nanostructures[J].Advanced functional materials,2005(1):161-167. |
[21] | Gole J L;Stout J D;Burda C et al.[J].Journal of Physical Chemistry B,2004,108:1230-1240. |
[22] | Kumar S;Fedorov AG;Gole JL .Photodegradation of ethylene using visible light responsive surfaces prepared from titania nanoparticle slurries[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2005(2):93-107. |
[23] | Nakano Y;Morikawa T;Ohwaki T et al.[J].Applied Physics Letters,2005,86:132104. |
[24] | Lee J Y;Park J;Cho J H .[J].Applied Physics Letters,2005,87:011904. |
[25] | Irie H;Wantanbe Y;Hashimoto K .[J].Journal of Physical Chemistry B,2003,107:5483-5486. |
[26] | Valentin C D;Pacchioni G;Selloni A .[J].Physical Review B,2004,70:085116. |
[27] | Batzill M;Morales E H;Diebold U .[J].Physical Review Letters,2006,96:026103. |
[28] | Li Yuanzhi;Hwang D S;Lee N H et al.[J].CHEMICAL PHYSICS LETTERS,2005,404:25-29. |
[29] | Choi Y;Umebayashi T;Yoshikaw M .[J].Journal of Materials Science,2004,39:1837-1839. |
[30] | Ohno, T;Tsubota, T;Toyofuku, M;Inaba, R .Photocatalytic activity of a TiO2 photocatalyst doped with C4+ and S4+ ions having a rutile phase under visible light[J].Catalysis Letters,2004(4):255-258. |
[31] | Shankar K;Paulose M;Mor GK;Varghese OK;Grimes CA .A study on the spectral photoresponse and photoelectrochemical properties of flame-annealed titania nanotube-arrays[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2005(18):3543-3549. |
[32] | Park J H;Kim S;Bard A J .[J].Nano Letters,2006,6(01):24-28. |
[33] | Nakano Y;Morikawa T;Ohwaki T .[J].Applied Physics Letters,2005,87:052111. |
[34] | Reddy K M;Baruwati B;Jayalakshmi M .[J].Journal of Solid State Chemistry,2005,178:3352-3358. |
[35] | Ohno T;Akiyoshi M;Umebayashi T .[J].Applied Catalysis A:General,2004,265:115-121. |
[36] | 周武艺,曹庆云,唐绍裘,刘英菊.硫掺杂纳米TiO2的掺杂机理及可见光催化活性的研究[J].无机材料学报,2006(04):776-782. |
[37] | Umebayashi T;Yamaki T;Itoh H .[J].Applied Physics Letters,2002,81(03):454-456. |
[38] | Umebayashi T;Yamaki T;Yamamoto S .[J].Journal of Applied Physics,2003,93(09):5156-5160. |
[39] | Hamal D B;Klabunde K J.[J].Journal of Colloid and Interface Science,2007 |
[40] | Yu J G;Yu J C;Cheng Bei et al.[J].Journal of Solid State Chemistry,2003,174:372-380. |
[41] | Di Li;Hajime Haneda;Shunichi Hishita;Naoki Ohashi;Nitin K.Labhsetwar .Fluorine-doped TiO_2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde[J].Journal of Fluorine Chemistry,2005(1):69-77. |
[42] | Di Li;Ohashi N;Hishita S et al.[J].Journal of Solid State Chemistry,2005,178:3293-3302. |
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