采用固相反应法制备了样品La0.67Sr0.33-xNaxMnO3(x=0.05,0.10,0.15,0.20,0.25,0.33).通过实验测出了样品的X射线衍射谱图、M-T曲线、p-T曲线和MR-T曲线,研究了Sr位掺Na对La0.67Sr0.33MnO3的晶格结构和磁电特性的影响.结果表明,样品呈菱面体结构,当x≥0.20时,Mn3+/Mn4+<1,体系在反铁磁态,但实验中所有样品表现为顺磁-铁磁相变伴随绝缘体.金属相变;随x增加,巨磁电阻MR增大,Tc降低,当x=0.33时,在室温区获得了很大的磁电阻MR=241%.
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