运用TEM和EDS等测试方法,对高铌X80管线钢连铸过程微合金元素的析出行为进行研究.结果表明:铸坯凝固冷却至1100℃时,存在片层状以及棒状析出物,此类析出物为Nb(C,N)碳氮化物,同时存在一些TiN析出物.当铸坯冷却至900℃时,开始出现中心富钛、边部富铌的(Nb,Ti)(C,N)星形和枝晶形碳氮化物.当铸坯冷却至750℃时,枝晶状析出物增多,同时也存在部分富铌的枝晶状Nb(C,N)碳氮化物.冷却至室温的铸坯晶界上存在大量的枝晶状析出物.由热力学计算和试验结果得出,对于高铌X80管线钢,枝晶状复合析出物开始析出温度介于1000~1100℃之间.
参考文献
[1] | 衣海龙,杜林秀,王国栋,刘相华.X80管线钢的组织与性能研究[J].东北大学学报(自然科学版),2008(02):213-216. |
[2] | Yong Zhong;Furen Xiao;Jingwu Zhang .In situ TEM study of the effect of M/A films at gram boundaries on crack propagation in an ultra-fine acicular ferrite pipeline steel[J].Acta materialia,2006(2):435-443. |
[3] | Yang J H;Liu Q Y;Sun D B et al.Recrystallization Beahvior of Deformed Austenite in High Strength Microalloyed Pipeline Steel[J].Journal of Iron and Steel Research International,2009,16(01):75. |
[4] | H.F. LOPEZ;R. RAGHUNATH;J.L. ALBARRAN;L. MARTINEZ .Microstructural Aspects of Sulfide Stress Cracking in an API X-80 Pipeline Steel[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,1996(11):3601-3611. |
[5] | S.G. Hong;H.J. Jun;K.B. Kang .Evolution of precipitates in the Nb-Ti-V microalloyed HSLA steels during reheating[J].Scripta materialia,2003(8):1201-1206. |
[6] | Hyun Jo Jun;K. B. Kang;C. G. Park .Effects of cooling rate and isothermal holding on the precipitation behavior during continuous casting of Nb-Ti bearing HSLA steels[J].Scripta materialia,2003(11):1081-1086. |
[7] | G.Zhou .The Evolution of Precipitates in Nb-Ti Microalloyed Steels during Solidification and Post-solidification Cooling[J].ISIJ International,1996(11):1397-1405. |
[8] | Craven A J;He K;Garvie L A J et al.Complex Heterogeneous Pecipitation in Titanium-Niobium Microalloyed Al-Killed HSLA Steels-I.(Ti,Nb)(C,N) Particles[J].Acta Materialia,2000,48(15):3857. |
[9] | J. S. Park;M. Ajmal .Tensile Properties of Simulated Thin Slab Cast and Direct Rolled Low-carbon Steel Microalloyed with Nb, V and Ti[J].ISIJ International,2000(4):380-385. |
[10] | Dutta B;Sellars C M .Effect of Composition and Process Variables on Nb(C,N) Precipitation in Niobium Microalloyed Austenite[J].Materials Science and Technology,1987,3(03):197. |
[11] | Akamatsu S;Hasebe M;Senuma T et al.Thermodynamic Calculation of Solute Carbon and Nitrogen in Nb and Ti Added Extra-Low Carbon Steels[J].ISIJ International,1994,34(01):9. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%