研究了Al2O3稀释剂添加量对NiO/Al体系燃烧速度及体系产物形貌的影响,结合绝热温度的计算结果,基于Merzhanov等提出的燃烧波速公式,根据体系In(v/Tnd)-1/Ld的Arrhenius图,测定了添加Al2O3后NiO/Al体系的反应激活能。研究结果表明:对于NiO/Al体系,在一定范围内(0~5%,25%~35%,质量分数)添加Al2O3稀释剂时,体系绝热温度与燃烧速度均不发生较大变化;体系的反应过程受到压块内铝反应物传质过程的影响,高于2740K时(Al反应物沸点温度),体系的表观反应激活能为(64±14)kJ/mol,温度低于2740K时,压块内的传质过程将以毛细作用为主,体系的反应激活能为(189±15)kJ/mol。
The effects of diluting agent Al2O3 on the combustion velocity and the products microstructurc of NiO/A1 aluminothermic system were studied. Combined with the adiabatic temperature calculation, the apparent activation energy of NiO/Al system were measured by Arrhenius diagram of ln(v/Tnd )- 1/Tnd~ based on the combustion equation proposed by Merzhanov et ah The results show that in a certain range of A1203 mass fraction (0-5%, 25%-35%), the combustion velocity of NiO/Al aluminothermic system is considerable invariable. The further results show that the process of combustion is contributed to the mass transferring of Al reactant of burning compact. When the temperature above the boiling point of Al(2740 K), the apparent activation energy of NiO/Al aluminothermic system is (64±14) kJ/mol. On the contrary, that is (189±15) kJ/mol.
参考文献
[1] | 傅正义. SHS技术研究进展——纪念SHS技术诞生三十周年 [J]. 复合材料学报, 2000, 17(1): 5-10. |
[2] | Merzhanov A G, Borovinskaya I P. Historical retrospective of SHS: An Autoreview [J]. International Journal of Self-Propagating High-Temperature Synthesis, 2008, 17(4): 242-265. |
[3] | Yi H C, Moore J J. Review: Self-propagating high-temperature(combustion) synthesis(SHS) of powder-compacted materials [J]. Journal of Materials Science, 1990, 25(2): 1159-1168. |
[4] | 汪 涛, 鲁玉祥, 祝美丽, 等. 燃烧合成动力学参数的研究进展 [J]. 材料导报, 2000, 14(12): 3-8. |
[5] | Wang L L, Munir Z A, Maximov Y M. Thermite reactions: Their utilization in the synthesis and processing of materials [J]. Journal of Materials Science, 1993, 28(14): 3693-3708. |
[6] | Pei J, Li J T, Liu G H, et al. Rapid fabrication of bulk graded Al2O3/YAG/YSZ eutectics by combustion synthesis under ultra-high-gravity field [J]. Ceramic International, 2009, 35(8): 3269-3273. |
[7] | 裴 军, 杨建辉, 梅 林, 等. 超重力场中熔融铸造透明YAG陶瓷的新技术 [J]. 硅酸盐学报, 2009, 37(10): 1669-1672. |
[8] | Pei J, Li J T, Liu G H, et al. Fabrication of bulk Al2O3 by combustion synthesis melt-casting under ultra-high gravity [J]. Journal of Alloys and Compounds, 2009, 476(1/2): 854-858.. |
[9] | Vrel D, Hendaouri A, Langlois P, et al. SHS reactions in the NiO-Al system: Influence of stoichiometry [J]. International Journal of Self-Propagating High-Temperature Synthesis, 2007, 16(2): 62-69. |
[10] | Sanin V N, Yukhvid V I, Sytschev A E, et al. Liquid-phase final product formed by an SHS reaction of NiO-Ni-Al system under microgravity conditions [J]. Microgravity and Science Technology, 2010, 22: 53-61. |
[11] | Sanin V N, Yukhvid V I, Sytschev A E, et al. The effect of microgravity on the composition of SHS products of the mixture NiO+Ni+Al+WC [J]. Inorganic Materials, 2009, 45(6): 635-644. |
[12] | 殷 声. 燃烧合成 [M]. 北京: 冶金工业出版社, 2004: 63-73.. |
[13] | Maglia F, Tanburini U A, Deidda C, et al. Role of mechanical activation in SHS synthesis of TiC [J]. Journal of Materials Science, 2004, 39: 5227-5230. |
[14] | 宋月鹏, 李江涛, 裴 军, 等. NiO/Al体系绝热温度的数值计算与试验验证 [J]. 复合材料学报, 2010, 27(3): 134-137. |
[15] | 宋月鹏, 李江涛, 林志明, 等. 燃烧合成Y3Al5O12 过程中铝粉粒度与压块密度对燃烧速率的影响 [J]. 硅酸盐学报, 2009, 37(2): 214-218. |
[16] | Lasalvia J C, Meyers M A. Combustion synthesis in the Ti-C-Ni-Mo system: Part Ⅱ-Analysis [J]. Metallurgical and Materials Transactions A, 1995(26A): 3011-3019. |
[17] | Holt J B, Kingman D D, Bianchini G M. Kinetics of the combustion synthesis of TiB2 [J]. Materials Science and Engineering, 1985, 71: 321-327. |
[18] | 裴 军. 氧化铝基陶瓷材料的超重力熔铸制备新技术研究 . 北京: 中国科学院理化技术研究所, 2009. |
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