化学激发钢渣基胶凝材料的抗压强度低,难以满足建筑材料对强度的要求;通过掺入少量硅灰以加速其水化反应,改善化学激发钢渣基胶凝材料的力学性能.当碱激发剂Na2SiO3·9H2O用量11wt%,硅灰掺量10wt%时,碱激发硅灰-钢渣基胶凝材料在室温养护28 d后,其抗压强度达56.7 MPa,较不掺硅灰的胶凝材料强度提高了59.72%.XRD、SEM及MIP结果表明:钢渣在碱激发作用下,随龄期的延长,氢氧化钙量逐渐减少,无定形的水化产物增多,微观结构更加致密,加入硅灰后,最可几孔径明显减小,无害孔的数量明显增多,导致其强度大幅度提高.
参考文献
[1] | 李辽沙.转炉渣资源化利用的历史沿革及趋势展望[J].世界钢铁,2011(04):62-67. |
[2] | 程绪想,杨全兵.钢渣的综合利用[J].粉煤灰综合利用,2010(05):45-49. |
[3] | S. Kourounis;S. Tsivilis;R.E. Tsakiridis .Properties and hydration of blended cements with steelmaking slag[J].Cement and Concrete Research,2007(6):815-822. |
[4] | Caijun Shi .Characteristics and cementitious properties of ladle slag fines from steel production[J].Cement and Concrete Research,2002(3):459-462. |
[5] | Hydration properties of basic oxygen furnace steel slag[J].Construction and Building Materials,2010(7):p.1134. |
[6] | Essia Belhadj;Cecile Diliberto;Andre Lecomte .Characterization and activation of Basic Oxygen Furnace slag[J].Cement & concrete composites,2012(1):34-40. |
[7] | 易龙生,温建.钢渣活性激发技术的研究现状和进展[J].硅酸盐通报,2013(10):2057-2062. |
[8] | 王亚超,张耀君,徐德龙.碱激发硅灰-粉煤灰基矿物聚合物的研究[J].硅酸盐通报,2011(01):50-54. |
[9] | Yao Jun Zhang;Li Cai Liu;Yong Xu;Ya Chao Wang;De Long Xu .A new alkali-activated steel slag-based cementitious material for photocatalytic degradation of organic pollutant from waste water[J].Journal of hazardous materials,2012(Mar.30):146-150. |
[10] | 范立瑛,王志.硅酸钠对脱硫石膏基钢渣复合材料性能的影响[J].21世纪建筑材料,2010(01):37-39. |
[11] | 许涛,卢都友,罗旌旺.偏高岭土和硅灰对三元胶凝材料的改性[J].南京工业大学学报(自然科学版),2012(02):67-72. |
[12] | C.K. Yip;G.C. Lukey;J.S.J. van Deventer .The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation[J].Cement and Concrete Research,2005(9):1688-1697. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%