报道了用改进的Bridgmam法生长的大尺寸PbWO4:(Sb,Y)晶体的光谱特性的表征研究.通过对依次切自大尺寸PbWO4:(Sb,Y)毛坯晶体的籽晶端、中间部位和顶端三块晶体(~23mm×23mm×20mm)的透射光谱、X射线激发发射光谱、紫外激发与发射光谱、发光衰减寿命、光产额和辐照损伤等方面的光谱性能测试,结果表明,Sb、Y双掺杂能显著改善PbWO4晶体的光谱性能,使晶体在短波330-420nm范围的透过率明显提高,光产额增加,抗辐照能力增强.但从籽晶端到顶端的性能存在一定的差异,说明大尺寸的PbWO4:(Sb,Y)晶体的均匀性还有待提高.
This paper presents the characterization and investigation of the optical properties on doubly-doped large PbWO4:(Sb,Y) crystals grown by the modified Bridgman method. Based on the comparison
measurement of the optical transmission spectra, X-ray excited luminescence, photoluminescence, decay time, light yield and irradiation damage for 23mm×23mm×20mm crystal samples
cut from seed end, middle part and top end of a large PbWO4:(Sb,Y) crystal ingot, the results show that co-doping Sb and Y can significantly improve the light yield, radiation hardness and other spectroscopic properties of PbWO4 crystal. However, the uniformity of large PbWO4:(Sb,Y) crystal needs to be further improved based on the comparison of measurement results.
参考文献
[1] | Kroger F A. Some Aspects of the Luminescence in solids, Elsevier, Amsterdam, 1948. [2] CMS Collaboration, The Compact Muon Solenoid-Technical Proposal, CERN/LHCC 94-38, LHCC/P1, Dec., 1994. [3] Lecoq P, Dafinei I, Auffray E, et al. Nucl. Instr. and Meth. A, 1995, 365: 291-298. [4] 冯锡淇, 殷之文(Feng Xiqi, et al). 无机材料学报(Journal of Inorganic Materaials), 1997, 12 (4): 449-456. [5] Zhang X, Liao J Y, et al. Chem. Phys. Lett., 2004, 383: 245-250. [6] Kobayashi M, Usuki Y, Ishii M, et al. Proceedings of SCINT 2003, Valencia, Spain. [7] Kobayashi M, Usuki Y, Ishii M, et al. Nucl. Instr. and Meth. A, 1999, 434: 412-423. [8] Annenkov A, Auffray E, Borisevich A, et al. Nucl.Instr. and Meth. A, 1999, 426: 486-490. [9] Qu X D, Zhang L Y, et al. Nucl. Instr. and Meth. A, 2002, 486: 89-92 . [10] Yang P Z, Liao J Y, Shen B F, et al. J. Cryst. Growth, 2002, 236: 589-595. [11] 廖晶莹(Liao jingying, et al).无机材料学报(Journal of Inorganic Materials), 1997, 12(3): 286-290. [12] 冯锡淇, 韩宝国, 胡关钦, 等. 物理学报, 1999, 48(7): 1282-1291. [13] NIKL M, Nitisch K, Baccaro S, et al. J. Appl. Phys., 1997, 82(11): 5758-5761. [14] Ling Q S, Feng X Q, et al. Phys. Stat. Sol. (a), 2000, 181: R1-R3. [15] Huang H W, Li W S, Feng X Q, et al. Phys. Stat. Sol. (a), 2001, 187: 563-567. [16] Huang Y L, Zhu W L, Feng X O, et al. J. Sol. Stat. Chem., 2003, 172: 188-193. |
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