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为开发在超高温、大温差条件下具有热应力缓和功能的新型耐磨耐蚀涂层,在钛合金表面Nd∶YAG激光制备了梯度功能涂层,SEM观察了微观组织结构,XRD分析相组成并测定了摩擦磨损和耐腐蚀性能。结果表明原位自反应生成的TiC球状增强体弥散均匀分布在FGL中,微观组织为粗大和不完整的树枝晶、相对较细小的等轴和近等轴晶及细小短纤维状形态。FGL和N-FGM耐磨、耐蚀性能优异;摩擦系数和磨损率显著降低,其平均值是Ti600基体的0.3~0.5倍;腐蚀电流和电阻值分别为Ti600的0.72和1.31倍。

To improve the wear and corrosion resistance of Ti600,and alleviate thermal stress as well under hyperthermal and excessive temperature difference condition,the experiments of Ti-matrix FGL on Ti600 substrate by pulsed Nd∶YAG had been carried out.The microstructures and phase composition of the FGL were investigated.The friction wear and corrosion properties of the FGL,N-FGM and Ti600 substrate were examined.It was found that a rapidly solidified microstructure consisting of in situ synthesized TiC reinforced phase distributed on FGL substance evenly and dispersely in the form of globular grains had three main different shapes:bulky or imperfect arborescent crystal,fine or approximately equiaxial crystal and chopped fibriform crystal.The wear and corrosion resistance of the FGL was improved.Friction coefficient and wear rate decreased significantly,the value was 0.3-0.5 times of Ti600 substrate.Corrosion current and resistance were 0.72 and 1.31 times of Ti600 substrate separately.

参考文献

[1] 崔爱永,胡芳友,回丽.钛合金表面激光熔覆(Ti+Al/Ni)/(Cr2O3+CeO2)复合涂层组织与耐磨性能[J].中国激光,2007(03):438-441.
[2] 张琳,吴荫顺,曹备,丁宝峰.钛合金材料在醇类溶液中的电化学行为[J].北京科技大学学报,2003(02):163-166.
[3] 周国定,Kamkin A N,廖强强.钛钼合金电极在酸性介质中的电化学研究[J].腐蚀与防护,2005(08):323-325.
[4] 孙荣禄,刘勇,杨德庄.钛合金表面激光熔覆NiCrBSi-TiC复合涂层的组织和摩擦磨损性能[J].中国激光,2003(07):659-662.
[5] 张松,张春华,康煜平,吴维,王茂才,文交/力忠.钛合金表面激光熔覆原位生成TiC增强复合涂层[J].中国有色金属学报,2001(06):1026-1030.
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