通过对掺杂不同含量钨精矿粉末Fe-Al系粉末压坯进行激光点燃自蔓延烧结(SHS),利用XRD、SEM、硬度测试、磨损测试表征手段,分析研究了钨精矿粉含量对烧结合金微观组织结构及宏观性能的影响。实验结果表明:在烧结过程中,压坯实现了自蔓延燃烧。合金组织为针状组织,且随着钨精矿粉含量的增加,针状组织长大。产物物相主要为AlFe、AlFe3、WO3以及Fe7W6。当钨精矿粉添加量为1%时,烧结合金显微硬度最大,达到HK956,烧结合金的密度最大,为4.27g/cm3,孔隙率最小,为12.2%,烧结合金的相对磨损率最低,达到0.05%。
Fe-Al alloy blended with different levels of tungsten concentrate powder was prepared by laser ignition induced self-propagating high-temperature synthesis(SHS).By means of the XRD,SEM,hardness test and abrasion test,the effect of the content of tungsten concentrate powder on the sintered alloy microstructure and macroscopic properties was studied.The experimental results show that through the sintering process,the self-propagating combustion synthesis of the blank was achieved.The structures of the sintered alloy are acicular,which grow up with the increase of the content of tungsten concentrate powder.The product phase of the sintering alloy are AlFe,AlFe3,WO3 and Fe7W6.When the mass fraction of the tungsten concentrate powder is 1%,the micro-hardness and the density of the sintering alloy are both the biggest,which are HK956 and 4.27 g/cm3 respectively,while the porosity and the relative wear rate of the sintering alloy are the lowest,which are 12.2% and 0.05% respectively.
参考文献
[1] | 殷声.燃烧合成[M].北京:冶金工业出版社,2004:1-2,35-36. |
[2] | 顾小颜.赵海云.激光诱导自蔓延高温合成技术[C]//第十一次全国焊接会议论文集.上海:中国机械工程学会焊接学会,2005 |
[3] | 姚健奎,李言祥,宋晋升.激光控制反应合成的实验研究[J].应用激光,2002,22(2):113-118. |
[4] | 杨永强,刘春雷,朱敏.激光诱导自蔓延MgNi合金[J].新技术新工艺,2003(10):45-47. |
[5] | 王存山,夏元良,李刚,等.激光诱导自蔓延反应合成非晶复合材料组织与性能[J].中国激光,2003,30(5):471-475. |
[6] | 陈雷.激光自蔓延烧结功能梯度材料的研究[D].吉林:吉林大学,2003:2. |
[7] | Pint BA, Zhang Y, Walker L R, et al. Long- term performance of aluminide coatings on Fe-base alloy[J]. Surf Coat Technol, 2007, 202(4-7): 637-642. |
[8] | 望斌,彭志方,周元贵,等.Fe-Al金属间化合物材料的强化机理及其高温性能研究现状[J].材料导报,2007,21(7):63-67. |
[9] | 王峰,奚正平,汤慧萍,等.Fe-Al合金多孔材料研究进展[J].粉末冶金技术,2010,28(6):463-466. |
[10] | 徐滨士,朱子新,刘燕,等.高速电弧喷涂Fe-A1金属间化合物涂层[J].中国有色金属学报,2004.14(1):154-158. |
[11] | 望斌,彭志方,张凡,等.粉末冶金制备Fe-A1金属问化合物材料研究进展[J].材料导报,2007,21(1):75-79. |
[12] | 高海燕,贺跃辉,沈培智.FeAl金属间化合物研究现状[J].材料导报,2008,22(7):68-71. |
[13] | Sikka V K, Wilkening D, Liebetrau J, et al. Melting and casting of FeA1 based east alloy [J]. Materials Science Engineering A, 1998, 258(1): 229-235. |
[14] | Kcch C C. Intermetallic matrix composite prepared by mechanical alloying: A review [J]. Materials Science Engineering A, 1998, 244(1): 39-48. |
[15] | 高海燕,贺跃辉,沈培智,等.FeAl多孔材料与不锈钢的焊接[J].中国有色金属学报,2009,19(1):90-95. |
[16] | 宋海霞,吴运新,巩前明,等.B2型FeAl金属间化合物的制备及性能研究进展[J].粉末冶金技术,2009,27(5):381-386. |
[17] | Paul A, van Dal M J H, Kodentsov A Kirkendall effect in multiphase diffusion [J]. 2004, 52(3): 623-630. |
[18] | Bouayad A, Gerometta C, Belkebir A, interactions between solid iron and molten Mater Sci Eng A, 2003, 363(1/2): 53-61 |
[19] | Nakamura R, Takasawa K, Yamazaki Y, et al. Single- phase interdiffusion in the B2 type intermetallic compounds NiAI, CoAl and FeA1[J]. Intermetallics, 2002, 10(2): 195-204. |
[20] | 杨瑞成,陈奎,王凯旋,等.WC/NiCrMo钢基复合材料的断裂行为及特征[J].复合材料学报,2005,22(3):130-134. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%