通过柠檬酸低温燃烧法合成了A位缺位的(La06Sr1.4)1-xMgMoO6-δ(x=0,0.02,0.04,0.06,0.08,0.1)固体氧化物燃料电池阳极材料.系统研究了A位缺位量对材料晶体结构、电导率以及电化学性能的影响规律.研究结果表明,A位缺位的LSMM均为双钙钛矿相结构,在5％H2/Ar还原气氛中经1250℃煅烧10 h具有良好的结构稳定性.A位缺位提高了LSMM在空气中的结构稳定性,随着缺位量的增加材料的电子电导率逐渐减小,阳极的极化电阻逐渐减小,电池的功率密度逐渐增加.
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