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按照正负离子未分开的条件分别对含固溶体、共晶体和复杂化合物的二元熔盐制定了作用浓度计算模型,计算结果与实测活度符合;按照正负离子分开的条件制定的计算模型,则未取得符合实际的结果,证明熔盐中正负离子的确是未分开的,原因是多数熔盐中缺乏介电物质.

Calculating models of mass action concentrations have been formulated for molten binary salt systems involving solid solution, eutectic and compound formation respectively according to the condition that cations and anions combine together during reaction. The agreement between calculated and measured values is very well, while opposite results would get when the cations and the anions separate from each other. This shows that the cations and the anions combine together during reaction indeed, because of the deficiency of dielectric material for most molten salts.

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