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通过液相还原法制备出金-银复合纳米颗粒.透射电镜图像显示所制备金-银复合纳米颗粒呈球状的芯-壳结构.光学吸收谱的实验表明:金芯-银壳复合结构纳米微粒具有双峰的等离子体吸收带.一个峰值的波长位于纯银纳米颗粒的等离子体吸收带附近;另一个介于纯银和纯金纳米颗粒的等离子体吸收峰之间,且随着反应试样中银的摩尔分数的增加发生蓝移,基于实验分析和Mie散射理论的定量计算.结果认为:该吸收峰的蓝移可归因于银壳层厚度的增加.

参考文献

[1] Kamat P V .[J].Journal of Physics and Chemistry of Solids,2002,106(32):7729.
[2] Klabunde K J.Nanoscale Materials in Chemistry[M].New York:Wiley,2001:121.
[3] Feldheim D L;Jr Foss C A.Metal Nanoparticles:Synthesis,Characterization and Application[M].New York:Marcel Dekker,2002:89.
[4] Graf C.;van Blaaderen A. .Metallodielectric colloidal core-shell particles for photonic applications[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(2):524-534.
[5] Caruso F.;Susha A.;Giersig M.;Caruso RA.;Spasova M. .Magnetic nanocomposite particles and hollow spheres constructed by a sequential layering approach[J].Chemistry of Materials,2001(1):109-116.
[6] Bohren C F.Absorption and Scattering of Light by Small Particles[M].New York:Wiley,1983:130.
[7] Averitt R D;Westcott S L;Halas N J .[J].Journal of the Optical Society of America B:Optical Physics,1999,16(10):1824.
[8] Grabar K C et al.[J].Annali di Chimica,1995,67:735.
[9] Averitt RD;Sarkar D;Halas NJ .Plasmon resonance shifts of Au-coated Au2S nanoshells: Insight into multicomponent nanoparticle growth[J].Physical review letters,1997(22):4217-4220.
[10] Neeves A E;Brinboim M H .[J].Journal of the Optical Society of America B:Optical Physics,1989,6(04):787.
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