通过液相还原法制备出金-银复合纳米颗粒.透射电镜图像显示所制备金-银复合纳米颗粒呈球状的芯-壳结构.光学吸收谱的实验表明:金芯-银壳复合结构纳米微粒具有双峰的等离子体吸收带.一个峰值的波长位于纯银纳米颗粒的等离子体吸收带附近;另一个介于纯银和纯金纳米颗粒的等离子体吸收峰之间,且随着反应试样中银的摩尔分数的增加发生蓝移,基于实验分析和Mie散射理论的定量计算.结果认为:该吸收峰的蓝移可归因于银壳层厚度的增加.
参考文献
[1] | Kamat P V .[J].Journal of Physics and Chemistry of Solids,2002,106(32):7729. |
[2] | Klabunde K J.Nanoscale Materials in Chemistry[M].New York:Wiley,2001:121. |
[3] | Feldheim D L;Jr Foss C A.Metal Nanoparticles:Synthesis,Characterization and Application[M].New York:Marcel Dekker,2002:89. |
[4] | Graf C.;van Blaaderen A. .Metallodielectric colloidal core-shell particles for photonic applications[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(2):524-534. |
[5] | Caruso F.;Susha A.;Giersig M.;Caruso RA.;Spasova M. .Magnetic nanocomposite particles and hollow spheres constructed by a sequential layering approach[J].Chemistry of Materials,2001(1):109-116. |
[6] | Bohren C F.Absorption and Scattering of Light by Small Particles[M].New York:Wiley,1983:130. |
[7] | Averitt R D;Westcott S L;Halas N J .[J].Journal of the Optical Society of America B:Optical Physics,1999,16(10):1824. |
[8] | Grabar K C et al.[J].Annali di Chimica,1995,67:735. |
[9] | Averitt RD;Sarkar D;Halas NJ .Plasmon resonance shifts of Au-coated Au2S nanoshells: Insight into multicomponent nanoparticle growth[J].Physical review letters,1997(22):4217-4220. |
[10] | Neeves A E;Brinboim M H .[J].Journal of the Optical Society of America B:Optical Physics,1989,6(04):787. |
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