用环氧树脂低聚物作界面增容剂,熔融挤出法制备了PA66/TLCP共混物.通过拉伸、弯曲等力学性能测试并结合热失重(TG)分析,结果表明:环氧树脂低聚物增容后的共混物力学性能、热稳定性均有显著提高.共混物断面SEM扫描结果表明,由于环氧树脂低聚物界面增容作用,分散相TLCP在基体PA66中的分散性提高并且相畴尺寸减小.加工流变学测试和红外光谱显示,环氧树脂低聚物与基体树脂PA66和分散相TLCP分子在熔融加工过程中原位发生化学反应,环氧树脂低聚物在共混物界面起到"桥"的作用.
参考文献
| [1] | Huang CC.;Chang FC. .REACTIVE COMPATIBILIZATION OF POLYMER BLENDS OF POLY(BUTYLENE TEREPHTHALATE) AND POLYAMIDE 6,6 .2. MORPHOLOGICAL AND MECHANICAL PROPERTIES[J].Polymer: The International Journal for the Science and Technology of Polymers,1997(17):4287-4293. |
| [2] | Tjong S.C.;Meng Y.Z. .Properties of ternary in situ polycarbonate/polybutylene terephthalate/liquid crystalline polymer composites[J].Journal of Applied Polymer Science,1999(7):1827-1835. |
| [3] | Tjong S.C. .Effect of reactive compatibilizers on the mechanical properties of polycarbonate/poly(acrylonitrile-butadienestyrene)blends[J].European Polymer Journal,2000(1):123-129. |
| [4] | Holstimiettinen RM.;Seppala JV.;Heino MT. .USE OF EPOXY REACTIVITY FOR COMPATIBILIZATION OF PP PBT AND PP LCP BLENDS[J].Journal of Applied Polymer Science,1995(5):573-586. |
| [5] | Jie W.;Li Y. .Tissue engineering scaffold material of nano-apatite crystals and polyamide composite[J].European Polymer Journal,2004(3):509-515. |
| [6] | Xiang Zhang;Yubao Li;Guoyu Lv;Yi Zuo Yuanhua Mu .Thermal and crystallization studies of nano-hydroxyapatite reinforced polyamide 66 biocomposites[J].Polymer Degradation and Stability,2006(5):1202-1207. |
| [7] | Jiasong He;Jie Liu .Miscibility enhancement of modified polystyrene blends with a liquid crystalline polymer[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(4):959-969. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%