采用极化曲线、交流阻抗、溶液分析等方法研究了苯并三氮唑(BTA)与碘化钾(KI)对天然海水中黄铜的协同缓蚀作用及加药顺序对缓蚀性能的影响.结果表明,当BTA和KI的使用浓度分别为2 mg/L和10 mg/L时,对黄铜的缓蚀率达到97.19%;考虑加药顺序后缓蚀率可进一步提高到99.31%.极化曲线测试表明,BTA与KI复配为混合型缓蚀剂,且抑制阴极反应的程度更强.SEM照片显示,添加了BTA与KI缓蚀剂的铜片表面基本没有腐蚀.溶液分析显示添加了BTA与KI复配缓蚀剂后有效地抑制了黄铜的脱锌腐蚀.
参考文献
| [1] | Ravichandran R;Nanjundan S;Rajendran N .Effect of benzotriazole derivatives on the corrosion of brass in NaCl solutions[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1/4):241-250. |
| [2] | Kabasakaloglu M.;Kiyak T.;Sendil O.;Asan A. .Electrochemical behavior of brass in 0.1 M NaCl[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2002(1/4):167-174. |
| [3] | Sherif ESM .Effects of 2-amino-5-(ethylthio)-1,3,4-thiadiazole on copper corrosion as a corrosion inhibitor in 3% NaCl solutions[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(24):8615-8623. |
| [4] | E.M. Sherif;Su-Moon Park .2-Amino-5-ethyl-1,3,4-thiadiazole as a corrosion inhibitor for copper in 3.0% NaCl solutions[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2006(12):4065-4079. |
| [5] | Ai JZ;Guo XP;Qu JE;Chen ZY;Zheng JS .Adsorption behavior and synergistic mechanism of a cationic inhibitor and KI on the galvanic electrode[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2006(1/3):147-155. |
| [6] | E.E. Oguzie;Y. Li;F.H. Wang .Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion[J].Journal of Colloid and Interface Science,2007(1):90-98. |
| [7] | M.A. Deyab .Effect of cationic surfactant and inorganic anions on the electrochemical behavior of carbon steel in formation water[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(5):2315-2328. |
| [8] | A. Dermaj;N. Hajjaji;S. Joiret;K. Rahmouni;A. Srhiri;H. Takenouti;V. Vivier .Electrochemical and spectroscopic evidences of corrosion inhibition of bronze by a triazole derivative[J].Electrochimica Acta,2007(14):4654-4662. |
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