本文应用蒙特卡罗方法建立了汽油机三元催化器(TWC)芳香烃演化模型,并使用实际发动机的实验结果对该模型进行了验证,结果表明该模型与实际基本相符.同时根据计算证明了,烷基苯催化重整加氢脱烷基生成苯,是三元催化器中苯生成的一个途径.而且发现了三元催化器中苯生成的另一个途径,烷基苯部分氧化生成苯,而且在某些工况该反应起主要作用.
参考文献
[1] | Westerholm R N;Alsberg T E et al.Effect of Fuel Polycyclic Aromatic Hydrocarbon Content on the Emissions of Polycyclic Aromatic Hydrocarbon Content and Other Mutagenicity Substances from a GasolinefuelAutomobile[J].Environmental Science and Technology,1988,22:925-930. |
[2] | STEFAN BRUEHLMANN;ANNA-MARIA FORSS;DOMINIK STEFFEN;NORBERT V. HEEB .Benzene: A Secondary Pollutant Formed in the Three-Way Catalyst[J].Environmental Science & Technology: ES&T,2005(1):331-338. |
[3] | U S EPA.Carcinogenic Effects of Benzene:An Update; EPA/600/P-97/001-F[M].U S Environmental Protection Agency:Washington,DC,1998 |
[4] | Heeb NV.;Forss AM.;Weilenmann M. .Pre- and post-catalyst-, fuel-, velocity- and acceleration-dependent benzene emission data of gasoline-driven EURO-2 passenger cars and light duty vehicles[J].Atmospheric environment,2002(30):4745-4756. |
[5] | Bruehlmann S;Novak P;Lienemann P;Trottmann M;Gfeller U;Zwicky CN;Bommer B;Huber H;Wolfensberger M;Heeb NV .Three-way-catalyst induced benzene formation: A precursor study[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(26):276-283. |
[6] | 郭向云,李永旺,王琴,罗庆云,钟炳.甲烷化反应机理的蒙特卡罗模拟[J].燃料化学学报,1994(02):215-218. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%