欢迎登录材料期刊网

材料期刊网

高级检索

利用熔点、玻璃化转变温度等易获得的参数并结合准规则模型以及生成热模型,给出了一种计算多元系非晶合金粘度的热力学方法.利用该方法计算了Zr基和Fe基大块非晶合金系的粘度,计算结果与经验结果吻合较好.计算表明,同一温度下,多组元合金系粘度值随组元数增加而增大,粘度随着过冷度的增加而增大;Zr-Al-Ni三元合金在xZr =0.375~0.8571、xNi=0~0.357成分范围内,Zr-Al-Cu三元合金在xzr=0.375~0.8625、xcu =0~0.400成分范围内,Zr66.7Al-Ni-Cu系在xAl=0.632~0.809、xNi=0.145~0.245成分范围内粘度较高;对Fe-基块体合金系,Fe-Nb-B合金系在xNb=0.325~0.9375、xB=0.0625~0.675成分范围内,Fe-Si-B合金在xSi=0~0.521、xB=0.5124~0.9375成分范围内粘度较高.

参考文献

[1] Chiriac H;Tomut M;Grigorica M .On the viscosity near the melting point of some liquid glass-forming transition metal alloys[J].Journal of Non-Crystalline Solids,1996,205:504.
[2] 周晓薇,陈金玉.液态金属粘滞性的研究进展[J].沈阳师范大学学报(自然科学版),2003(04):255-259.
[3] 郑福前.金属玻璃Ni30Zr70的动态粘度和稳态粘度[J].物理学报,1991(02):262-268.
[4] Robertson CG.;Roland CM.;Santangelo PG. .Comparison of glass formation kinetics and segmental relaxation in polymers[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2000(3):153-159.
[5] Heermann D W.Computer simulation methods in theoretic physics[M].北京:北京大学出版社,1996:16.
[6] 惠西东;陈国良.大块非晶合金[M].北京:化学工业出版社,2004:78.
[7] Hoffmann K H.Computational physics[M].北京:科学出版社,2001:10.
[8] 张晖,张秉坚,梁世强,路映红,胡文暄.微孔中简单流体粘度的分子动力学模拟及关联模型[J].物理化学学报,2003(04):352-355.
[9] 范庆梅,卢文强.纳米流体热导率和粘度的分子动力学模拟计算[J].工程热物理学报,2004(02):268-270.
[10] Yokoyama I.;Tsuchiya S. .Correlation entropy and its relation to properties of simple liquid metals[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2002(0):232-235.
[11] 刘燕,耿浩然,孙民华,崔红卫.液态金属粘滞性的研究现状与展望[J].铸造,2000(12):875-878.
[12] 耿浩然,孙春静,杨中喜,王瑞,吉蕾蕾.金属熔体黏度与结构相关性的分子动力学模拟[J].物理学报,2006(03):1320-1324.
[13] T. Koishi;Y. Shirakawa;S. Tamaki .Simulation of shear viscosity in liquid metals[J].Computational Materials Science,1996(3):245-253.
[14] Morilka S;Bian X F;Sun M H .A model of viscosity for liquid metals[J].Zeitschrift fur Metallkunde,2002,93(04):288.
[15] Morioka S .The dense gas-like model of the viscosity for liquid metals[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(1/3):46-52.
[16] Morioka S .Evaluation of the viscosity for binary and ternary liquid alloys[J].Materials Science and Engineering,2003,362(1-2):223.
[17] Battezzati L;Greer A L .The viscosity of liquid metals and alloys[J].Acta Metallurgica,1989,37(07):1791.
[18] Zhong X M;Chou K C;Gao Y M et al.Estimating ternary viscosity in terms of moelwyn-hughes model[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,2001,25(03):455.
[19] Johnson W L;Lu J .Deformation and flow in bulk metallic glasses and deeply undercooled glass forming liquids a selfconsistent dynamics free volume model[J].Intermetallics,2002,10(11-12):1039.
[20] Fecht H J .Thermodynamic properties of amorphous solidsglass formation and glass transition[J].Materials Transactions,1995,36(07):777.
[21] Ghosh G .Thermodynamics and kinetics of stable and metastable phases in the Ni-Zr system[J].Journal of Materials Research,1994,9(03):598.
[22] Goken N A.Statistical thermodynamics of alloys[M].New York:Plenum Press,1986:255.
[23] 丁学勇.合金熔体热力学模型、预测值及其软件开发[M].沈阳:东北大学出版社,1998:10.
[24] 魏庆成.冶金热力学[M].重庆:重庆大学出版社,1996:73.
[25] Lupis C H;Elliott J F .Prediction of enthalpy and entropy interaction coefficients by the "central atoms” theory[J].Acta Metallurgica,1989,15(02):265.
[26] Takeuchi K.;Inoue A. .Quantitative evaluation of critical cooling rate for metallic glasses[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2001(0):446-451.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%