采用Czochralski法生长了Li_(0.067)Na_(0.933)Tb(MoO_4)_2晶体,并测试了Li~+在NaTb(MoO_4)_2晶体中的有效分凝系数.由粉末X射线衍射数据计算了晶体的晶胞参数.室温下,采用消光法测试了Li_(0.063)Na_(0.933)Tb(MoO_4)_2晶体在532 nm、633 nm和1064 nm处的费尔德常数,分别为-293.6 rad·m~(-1)·T~(-1)、-200.5 rad·m~(-1)·T~(-1)和-68.6 rad·m~(-1)·T~(-1),与纯NaTb(MoO_4)_2相比,其费尔德常数均有所增加.结果表明,在1064 nm处Li_(0.067)Na_(0.933)Tb(MoO_4)_2晶体有较高的磁光优值.
Li_(0.067)Na_(0.933)Tb(MoO_4)_2 magneto-optical crystal was grown by the Czochralski method. The effective segregation coefficient of Li~+ in NaTb(MoO_4)_2 was measured. The lattice parameters of the crystal were determined by XRD data. Verdet constants of Li 0.067Na0.933Tb(MoO4)2 crystal at the wavelength 532 nm, 633 nm and 1064 nm were investigated by the extinction method at room temperature. They are -293.6 rad·m~(-1)·T~(-1),-200.5 rad·m~(-1)·T~(-1) and -68.6 rad·m~(-1)·T~(-1), respectively, and are larger than that of pure NaTb(MoO_4)_2 at corresponding wavelengths. The results showed that Li_(0.067)Na_(0.933)Tb(MoO_4)_2 has a larger magneto-optical figure of merit at 1064 nm wavelength.
参考文献
[1] | Geho M;Sekijima T;Fujii T .Growth Mechanism of Incongruently Melting Terbium Aluminum Garnet (Tb_3Al_5O_(12);TAG) Single Crystals by Laser FZ Method[J].Journal of Crystal Growth,2005,275(1-2):e663-e667. |
[2] | Rubinstein C B;Uitert L G V;Grodkiewicz W H .Magneto-optical Properties of Rare Earth (III) Aluminum Garnets[J].Applied Physics,1964,35:3069. |
[3] | Raja M Y A;Allen D;Sisk W .Room-temperature Inverse Faraday Effect in Terbium Gallium Garnet[J].Applied Physics Letters,1995,67:2123. |
[4] | Sugg B;Nürge H;Faust B et al.The Photorefractive Effect in Terbium Gallium Garnet[J].Optical Materials,1995,4(2-3):343-347. |
[5] | Linares C R .Growth of Garnet Laser Crystals[J].Solid State Communications,1964,2(08):229-231. |
[6] | Jingjing Liu;Feiyun Guo;Bin Zhao;Naifeng Zhuang;Yanping Chen;Zhaoping Gao;Jianzhong Chen .Growth and magneto-optical properties of NaTb(WO_4)_2[J].Journal of Crystal Growth,2008(10):2613-2616. |
[7] | Feiyun Guo;Jingjing Ru;Hongzhe Li;Naifeng Zhuang;Bin Zhao;Jianzhong Chen .Growth and magneto-optical properties of NaTb(MoO_4)_2 crystals[J].Journal of Crystal Growth,2008(19):4390-4393. |
[8] | Kuz'micheva G M;Lis D A;Subbotin K A et al.Growth and Structural X-ray Investigations of Scheelite-like Single Crystals Er,Ce:NaLa(MoO_4)_2 and Yb:NaGd(WO_4)_2[J].Journal of Crystal Growth,2005,275(1-2):e1835-e1842. |
[9] | Xiuzhi Li;Zhoubin Lin;Lizhen Zhang;Guofu Wang .Growth and spectral properties of Yb~(3+)-doped NaY(MoO_4)_2 crystal[J].Optical materials,2007(6):728-731. |
[10] | X. Chen;B. Lavorel;J. P. Boquillon;R. Saint-Loup;M. Jannin .Optical rotary power at the resonance of the terbium {sup}7F{sub}6--{sup}5D{sub}4 line in terbium gallium garnet[J].Solid-State Electronics,1998(9):1765-1766. |
[11] | 陈敬中.现代晶体化学-理论与方法[M].北京:高等教育出版社,2001:93. |
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