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选取TA2纯钛为研究对象,在箱式电阻炉中进行不同温度与不同时间的热氧化处理,研究了不同工艺热氧化处理试样在36%~38%HCl(室温)和30%H2O2(36.5℃)中的耐腐蚀性。采用扫描电子显微镜(SEM)观察了热氧化处理试样表面形貌, XRD进行了物相分析,用电子天平称重。研究结果表明, TA2纯钛在600℃以上热氧化处理在其表面形成了比原始态更厚的金红石型TiO2氧化膜,且TiO2氧化膜随热氧化温度升高而加厚;热氧化后TA2试样在36%~38%HCl和30%H2 O2中耐腐蚀性明显改善,改善TA2耐蚀性的最佳热氧化工艺条件为:热氧化温度700℃;热氧化时间330~500 min。

Commercially pure titanium ( CP-Ti) TA2 samples were subjected to thermal oxidation ( TO) treatment at different temperature .The morphological feature , structural characteristics and weight of thermally oxidized samples were studied by scanning electron microscope (SEM), X-ray diffraction(XRD) and electronic balance.The corrosion resistance of thermally oxidized samples in 36%~38% HCl ( room temperature ) and 30% H2 O2 ( 36.5 ℃) were investigated .The results show that , when the TO temperature is above 600 ℃, the oxidized layer is composed of TiO2 , and the thickness of TiO 2 oxidized layer increases with the temperature increased .And the corrosion resistance in HCl and H 2 O2 increases significantly after TO treatment , and the optimum TO condition is treating temperature of 700 ℃and duration of 330~500 min.

参考文献

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