在水溶性壳聚糖/鸡蛋清的调控下,采用气相扩散法仿生制备出多种形貌的碳酸钙晶体.研究了Ca2+起始浓度、m壳聚糖∶ m鸡蛋清质量比对碳酸钙形貌和晶型的影响.采用扫描电子显微镜(SEM)、红外光谱(FT-IR)及X射线衍射(XRD)等测试技术对获得的碳酸钙样品进行表征.XRD及FT-IR结果表明所得碳酸钙包括方解石和球霰石两种晶型,SEM观察表明Ca2+浓度及m壳聚糖∶m鸡蛋清质量比对碳酸钙形貌有重要的调控作用.
参考文献
[1] | Mann S .Molecular Recognition in Biomineralization[J].Nature,1988,332(10):119-124. |
[2] | Lowenstam H A;Weiner S.On Biomineralization[M].New York:Oxford Univeristy Press,1989 |
[3] | Jackson A P;Vincent J F V;Turner R M .The Mechanical Design of Nacre[J].Proceedings of the Royal Society B:Biological Sciences,1988,234(1277):415-440. |
[4] | Curre J D;Tayl J D .The Mechanical Behavior of Some Molluscan Hard Tissues[J].Journal of Zoology(London),1974,173:395-406. |
[5] | Song F;Soh AK;Bai YL .Structural and mechanical properties of the organic matrix layers of nacre.[J].Biomaterials,2003(20):3623-3631. |
[6] | Mann S.Biomineralization:Principles and Concepts in Bioinorganic Materials Chemistry[M].New York:Oxford Univeristy Press,2001 |
[7] | Elfil H;Roques H .Role of Hydrate Phases of Calcium Carbonate on the Scaling Phenomenon[J].Desalination,2001,137(1-3):177-186. |
[8] | Antonino Natoli;Matthias Wiens;Heinz-Christoph Schroder;Mauro Stifanic;Renato Batel;Analia L. Soldati;Dorrit E. Jacob;Werner E. G. Muller .Bio-vaterite formation by glycoproteins from freshwater pearls[J].Micron: The international research and review journal for microscopy,2010(4):359-366. |
[9] | 张勇,肖锐,凌立,谢莉萍,任燕,张荣庆.珍珠质水溶性基质蛋白的分离纯化及其对碳酸钙结晶的影响[J].海洋科学,2004(01):33-37,42. |
[10] | Gower LA.;Tirrell DA. .Calcium carbonate films and helices grown in solutions of poly(aspartate)[J].Journal of Crystal Growth,1998(1/2):153-160. |
[11] | 胡艳丽,马拥军,罗庆平,周勇,裴重华.L-天冬氨酸诱导叠层碳酸钙微晶的形成[J].人工晶体学报,2010(03):802-806,812. |
[12] | Colfen H.;Antonietti M. .Crystal design of calcium carbonate microparticles using double-hydrophilic block copolymers[J].Langmuir: The ACS Journal of Surfaces and Colloids,1998(3):582-589. |
[13] | Wei H;Shen Q;Zhao Y;Zhou Y;Wang DJ;Xu DF .On the crystallization of calcium carbonate modulated by anionic surfactants[J].Journal of Crystal Growth,2005(3/4):439-446. |
[14] | Po Liang;Ying Zhao;Qiang Shen;Dujin Wang;Duanfu Xu .The effect of carboxymethyl chitosan on the precipitation of calcium carbonate[J].Journal of Crystal Growth,2004(4):571-576. |
[15] | Hen eggwhite-mediated stack crystallization of calcium carbonate[J].Journal of Crystal Growth,2010(6):831. |
[16] | Addadi L;Moradian J;Shay E et al.A Chemical Model for the Cooperation of Sulfates and Carboxylates in Calcite Crystal Nucleation:Relevance to Biomineralization[J].Proceedings of the National Academy of Sciences(USA),1987,84(09):2732-2736. |
[17] | Chen SH;Soh AK .The capillary force in micro- and nano-indentation with different indenter shapes[J].International Journal of Solids and Structures,2008(10):3122-3137. |
[18] | Lad MD;Birembaut F;Frazier RA;Green RJ .Protein-lipid interactions at the air/water interface[J].Physical chemistry chemical physics: PCCP,2005(19):3478-3485. |
[19] | Xinran Liu;Bianhua Liu;Zhenyang Wang .Oriented Vaterite CaCO_3 Tablet-Like Arrays Mineralized at Air/Water Interface through Cooperative Regulation of Polypeptide and Double Hydrophilic Block Copolymer[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(26):9632-9636. |
[20] | Jiao YF;Feng QL;Li XM .The co-effect of collagen and magnesium ions on calcium carbonate biomineralization[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2006(4):648-652. |
[21] | Naka K.;Tanaka Y.;Chujo Y. .Effect of anionic starburst dendrimers on the crystallization of CaCO3 in aqueous solution: Size control of spherical vaterite particles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(9):3655-3658. |
[22] | Zhang Z P;Gao D M;Zhao H et al.Biomimetic Assembly of Polypeptide-Stabilized CaCO3 Nanoparticles[J].Journal of Physical Chemistry B,2006,110(17):8613-8618. |
[23] | Gelsomina De Stasio;Margaret A. Schmitt;Samuel H. Gellman .Spectromicroscopy at the organic-inorganic interface in biominerals[J].American Journal of Science,2005(6/7/8):673-686. |
[24] | Wang XQ;Sun HL;Xia YQ;Chen CX;Xu H;Shan HH;Lu JR .Lysozyme mediated calcium carbonate mineralization[J].Journal of Colloid and Interface Science,2009(1):96-103. |
[25] | Naoya Hosoda;Takashi Kato .Thin-Film Formation of Calcium Carbonate Crystals: Effect of Functional Groups of Matrix Polymers[J].Chemistry of Materials,2001(2):688-693. |
[26] | Ajikumar PK;Low BJM;Valiyaveettil S .Role of soluble polymers on the preparation of functional thin films of calcium carbonate[J].Surface & Coatings Technology,2005(1/3):227-230. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%