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对La-Al-Cu-Ni合金玻璃形成能力、热力学性能和力学性能进行了研究.结果表明,La62Al14Cu14Ni10大块金属玻璃具有较高的玻璃形成能力,其临界直径可达14 mm,另外具有较宽的过冷液相区(61 K),较低的玻璃转变温度(400 K).不同的玻璃形成能力在热力学框架内进行了讨论.La-Al-Cu-Ni合金玻璃形成能力与过冷液态区△Tx以及参数γ关系较小,且与约化玻璃转变温度Trg关系较大.La62Al14Cu17Ni7、La62Al14Cu14Ni10和La62Al14Cu12Ni12合金断裂强度超过600 MPa.该合金具有好的力学性能,可作为工程材料使用.

参考文献

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