利用热凝聚法合成四苯并卟啉锌的经典反应,加入过量的丁二酸钠代替原反应物乙酸钠,控制合成了中位-四(羧基亚甲基)苯并卟啉锌.由于羧基的引入,使卟啉分子能够锚定在二氧化钛表面.为转移卟啉激发态电子到二氧化钛的导带提供了通道,并改善了其在二氧化钛表面的分散性,从而使苯并卟啉锌敏化太阳能电池的效率明显提高.
参考文献
| [1] | 于哲勋,李冬梅,秦达,孙惠成,张一多,罗艳红,孟庆波.染料敏化太阳能电池的研究与发展现状[J].中国材料进展,2009(07):8-15. |
| [2] | Hwang S;Lee JH;Park C;Lee H;Kim C;Park C;Lee MH;Lee W;Park J;Kim K .A highly efficient organic sensitizer for dye-sensitized solar cells[J].Chemical communications,2007(46):4887-4889. |
| [3] | O'Regan B;Grtzel M .A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].Nature,1991,353:737. |
| [4] | Campbell W M;Burrell A K;Officer D L et al.Porphyrins as light harvesters in the dye-sensitised TiO2 solar cell[J].Coordination Chemistry Reviews,2004,248(13):1363. |
| [5] | 吴迪,沈珍,薛兆历,游效曾.卟啉类光敏剂在染料敏化太阳能电池中的应用[J].无机化学学报,2007(01):1-14. |
| [6] | Ruimin Ma;Ping Guo;Hongji Cui;Xianxi Zhang;Mohammad K. Nazeeruddin;Michael Gratzel .Substituent Effect on the Meso-Substituted Porphyrins: Theoretical Screening of SensitizerCandidates for Dye-Sensitized Solar Cells[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2009(37):10119-10124. |
| [7] | Balanay MP;Dipaling CVP;Lee SH;Kim DH;Lee KH .AM1 molecular screening of novel porphyrin analogues as dye-sensitized solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(19):1775-1781. |
| [8] | Jonathan Rochford;Dorothy Chu;Anders Hagfeldt;Elena Galoppini .Tetrachelate Porphyrin Chromophores for Metal Oxide Semiconductor Sensitization: Effect of the Spacer Length and Anchoring Group Position[J].Journal of the American Chemical Society,2007(15):4655-4665. |
| [9] | Deng HH.;Mao HF.;Lu ZH.;Zhou YM. .The mixed effect of phthalocyanine and porphyrin on the photoelectric conversion of a nanostructured TiO2 electrode[J].Synthetic Metals,1998(3):269-274. |
| [10] | Cherian S;Warnser C C .Adsorption and photoactivity of tetra(4-carboxyphenyl)porphyrin(TCPP)on nanoparticulate TiO2[J].Journal of Physical Chemistry B,2000,104(15):3624. |
| [11] | Kopranenkov V N;Makarova E A;Luk'yanets E A .Thermal condensation of phthalimide with malonic acid[J].Chem Heterocyclic Compd,1988,24(04):394. |
| [12] | Boucher L J;Katz J J .The infared spectra of metalloporphyrins(4000 ～ 160cm-1)[J].Journal of the American Chemical Society,1967,89(06):1340. |
| [13] | Edwards L;Gouterman M;Rose C B .Synthesis and vapor spectrum of zinc tetrabenzporphine[J].Journal of the American Chemical Society,1976,98(24):7638. |
| [14] | Ogoshi H;Saito Y;Nakamoto K .Infrared spectra and normal coordinate analysis of metalloporphins[J].Journal of Chemical Physics,1972,57:4194. |
| [15] | Qi MH.;Liu GF. .Synthesis and properties of transition metal benzoporphyrin compound liquid crystals[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(10):2479-2484. |
| [16] | Chen C Y;Wu S J;Wu C G et al.A ruthenium complex with superhigh light-harvesting capacity for dye-sensitized solar cells[J].Angewandte Chem Int Ed,2006,45:5822. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%