Ge23Se67Sb10玻璃的研制及其性能

稀有金属材料与工程, 2008, 37(4): 740-743.

Ge23Se67Sb10玻璃的研制及其性能

许军锋 ^1, , 坚增运 ^2, , 常芳娥 ^3, , 屈敏 ^4,

1.西安工业大学,陕西,西安,710032

2.西安工业大学,陕西,西安,710032

3.西安工业大学,陕西,西安,710032

4.西安工业大学,陕西,西安,710032

基金项目: 陕西省西安市科技攻关项目(GG0647) 陕西省薄膜技术与光学检测重点实验室开放课题(ZSKJ200502) 西安工业大学校科研和校改项目(XGYXJJ0516) 陕西省自然科学基金(2005E111)

关键词：硫系玻璃 , 玻璃转变温度 , 析晶温度 , 透过率

Preparation and Properties of Ge23Se67Sb10 Glass

对硫系玻璃的制备工艺及其性能进行了研究.制备出了致密均匀的Ge23Se67Sb10玻璃.所得玻璃的密度达到4.679g/cm3、显微维氏硬度达到1581 MPa.通过DSC测定,表明该材料的玻璃转变温度和开始析晶温度分别为261±2℃和402±1℃.通过傅里叶变换红外光谱测定,发现该材料在2～15 μm波长范围内的红外透过率达到60%左右.

参考文献

[1]	Zhang XH.;Guimond Y.;Bellec Y. .Production of complex chalcogenide glass optics by molding for thermal imaging[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(0):519-523.
[2]	Ma Hongli;Zhang Xianghua;Jacques Lucas .[J].Journal of Non-Crystalline Solids,2003,317:270.
[3]	Lezal D;Pedl Kov J;Hor K J .[J].Journal of Non-Crystalline Solids,1996,196:178.
[4]	Jacques Lucu .[J].Current Opinion in Solid State and Materials Science,1999,4:181.
[5]	Zakery A.;Elliott SR. .Optical properties and applications of chalcogenide glasses: a review [Review][J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(1/3):1-12.
[6]	Bureau Bruno;Zhang Xianghua;Frederic Smektala et al.[J].Journal of Non-Crystalline Solids,2004,345-346:276.
[7]	Daniel C Harris .[J].Infrared Physics & Technology,1998,39:185.
[8]	Sanghera Jas S;Shaw L Brandon;Ishwar D Aggarwal .[J].Comptes Rendus Chimie,2002,5:873.
[9]	Zhang X H .[J].Laser Focus World,2002,38(07):73.
[10]	韩铁,邱克强.NdYFeAl合金的非晶形成能力与磁性[J].稀有金属材料与工程,2003(11):907-910.
[11]	杨冠军,张涛,井上明久.Ta,Nb和Mo对Ti50Ni20Cu25Sn5非晶合金玻璃形成能力的影响[J].稀有金属材料与工程,2003(11):880-884.
[12]	Mehta N;Tiwari R S;Kumar A .[J].Materials Research Bulletin,2006,41(09):1664.
[13]	干福熹.光学玻璃[M].北京:科学出版社,1982:458.
[14]	Hilton A R;Hayes D J;Rechtin M D .[J].Journal of Non-Crystalline Solids,1975,17:319.
[15]	Kavetskyy TS.;Pamukchieva VD.;Shpotyuk OI.;Kovalskiy AP. .IR impurity absorption in Sb2S3-GeS2(Ge2S3) chalcogenide glasses[J].Infrared physics and technology,2000(1):41-45.
[16]	Sanghera J S;Aggarwal I D .[J].Journal of Non-Crystalline Solids,1999,256-257:6.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Ge23Se67Sb10玻璃的研制及其性能

Preparation and Properties of Ge23Se67Sb10 Glass

参考文献