用硅烷偶联剂( KH560)对纳米二氧化钛进行了改性,通过红外分光光度计对其改性效果做了表征。分别制备了含纳米二氧化钛5%、3%、2%、1%以及0%的TiO2/epoxy(二氧化钛/epoxy)的复合涂层,然后用BGD523 ABRASER型耐磨仪测试了涂层的耐磨性,并通过上海华晨电化学工作站( EIS)测定了复合涂层的阻抗,最后用热重分析仪( TGA)测定了耐热性以及用扫描电子显微镜观察了其表面形貌。结果表明:在空气环境下,纳米二氧化钛的加入能够提高其热稳定性;对于含不同比例的二氧化钛的TiO2/epoxy的复合涂层,当其含量为2%时,耐磨性和耐腐蚀性能均达到最高。
The silane coupling agent(KH560) was used to modify the TiO2 and its modification effect was characterized by infrared spectrophotometer. The powders containing 5%, 3%, 2%, 1%, and 0 of nano?TiO2 for the TiO2/epoxy composite coating were prepared, the wear resistance of the coating was tested by BGD523 ABRASER wear tester, the impedance of the composite coating was measured by EIS, the heat resistance was measured with thermogravimetric analyzer ( TGA ) , and finally the surface morphology was observed by scanning electron microscope. The results show that in the air circumstance, adding Nano?TiO2 can improve its thermal stability;for containing different proportions of TiO2 of the TiO2/epoxy composite coating, when its content is 2%, both of the wear resistance and corrosion resistance are the highest.
参考文献
[1] | 王永厚.实用涂料防腐手册[M].北京:冶金工业出版社,1994 |
[2] | 孔爱平,王军.基于化工设备金属腐蚀及环氧防腐涂层的应用研究[J].辽宁化工,2007(05):330-333. |
[3] | 边蕴静.纳米材料在涂料中的应用[J].化工新型材料,2001(07):32-32. |
[4] | 边蕴静.纳米材料在涂料中的应用[J].化工新型材料,2001(07):32-32. |
[5] | 陈宇飞;李连明;袁广雪 等.纳米二氧化钛表面化学改性及表征[J].哈尔滨师范大学自然科学学报,2011,27(04):71. |
[6] | 林鹏,浦丽莉,栾敏杰.硅烷偶联剂KH-560对粉石英的表面改性研究[J].黑龙江工程学院学报(自然科学版),2012(02):9-11. |
[7] | SOO-JIN P;JOONG-SEONG J.Effect of Silane Coupling Agent on Interphase and Performance of Glass Fibers/Unsaturated Polyester Composites[J].Journal of Colloid and Interface Science,2001(242):175-176. |
[8] | J?RG VOGELSANG;WEMER S.New interpretation of electrochemical data obtained from organic barrier coatings[J].Electrochimica Acta,2001(46):3818-3819. |
[9] | WANG Chaoxia;MAO Haiyan;WANG Chunxia.Dispersibility and Hydrophobicity Analysis of Titanium Dioxide Nanoparticles Grafted with Silane Coupling Agent[J].Industrial and Engineering Chemistry Research,2011(50):11932-11933. |
[10] | Dariusz Ozimina;Monika Madej;Tadeusz Kaldonski .The Wear Resistance of HVOF Sprayed Composite Coatings[J].Tribology letters,2011(1):103-111. |
[11] | 龚建彬,龙春光,粟洋,曹太山,周扬.基于原位反应制备CuO/PPS复合涂层的热性能和摩擦学性能[J].长沙理工大学学报:自然科学版,2012(02):87-91. |
[12] | 陈家才,王旭东,孙冬柏.氯离子在有机涂层中的渗透及涂层失效过程的电化学阻抗谱研究[J].材料工程,2011(06):52-57. |
[13] | 孔凡静,赵景茂.三种环氧富锌涂层在3.5% NaCl溶液中失效过程的电化学研究[J].腐蚀与防护,2012(06):489-493. |
[14] | 曹楚南;张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002 |
[15] | Liu Jianguo;Gong Gaoping;Yan Chuanwei .EIS study of corrosion behaviour of organic coating/Dacromet composite systems[J].Electrochimica Acta,2005(16/17):3320-3332. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%