金刚石膜拥有许多优异的性能。在制备金刚石膜的各种方法之中,高功率微波等离子体化学气相沉积(MPCVD)法因其产生的等离子体密度高,同时金刚石膜沉积过程的可控性和洁净性好,因而一直是制备高品质金刚石膜的首选方法。在世界范围内,美、英、德、日、法等先进国家均已掌握了以高功率MPCVD法沉积高品质金刚石膜的技术。但在我国国内,高功率MPCVD装备落后一直是困扰我国高品质金刚石膜制备技术发展的主要障碍.首先综述国际上高功率MPCVD装备和高品质金刚石膜制备技术的发展现状,包括各种高功率MPCVD装置的特点。其后,回顾了我国金刚石膜MPCVD技术的发展历史,并介绍北京科技大学近年来在发展高功率MPCVD装备和高品质金刚石膜制备技术方面取得的新进展。
Diamond films possess many remarkable properties. Among the various techniques to deposit diamond films,high power microwave plasma chemical vapor deposition (MPCVD) method has the advantages of high density plasma, good controllability and clean environment free from electrode material contamination. Therefore, MPCVD has remains the primary technique useful for depositing high quality diamond films. Western countries have developed abilities to deposit high quality diamond fihns by using high power MPCVD techniques. In contrast, slow development in high power MPCVD apparatus has remained a main obstacle for China to develop its ability to produce high quality diamond films material. In this article, we first review the evolution of high power MPCVD diamond films deposition techniques both abroad and at home. Then, we will present new results of our recent effort to develop high power MPCVD diamond films deposition techniques.
参考文献
[1] | Warlimont H;Weber E.Low-Press:tre Synthetic Ditzmnnd[M].Beilin:Springer-Verlag,1998 |
[2] | K.W. Hemawan;T.A. Grotjohn;D.K. Reinhard .Improved microwave plasma cavity reactor for diamond synthesis at high-pressure and high power density[J].Diamond and Related Materials,2010(12):1446-1452. |
[3] | Kamo M;Sato Y;Matsumoto S et al.Diamond Synthesis from Gas Phase in Microwaw:Plasma[J].Journal of Crystal Growth,1983,62(03):642-644. |
[4] | Bachmann P K;Messier A R .Emerging Technology of Diamond Thin Fihns[J].Chemical and Engineering News,1989,67(20):24-39. |
[5] | Bachmann P K;Leers D;Wiechert D U .Diamond Chemical Vapor Deposition[J].J de Physiqtte IV,1991,1(C2):907-913. |
[6] | Be;sen M M;Sevillano E;Smith D K .Microwave Plo.sma Reactor[P].USP 5556475,1993 -06 -04. |
[7] | Pleuler E;Wild C;Faner M et al.The CAP-Reactar,a Novel Microwave CVD System for Diamond Deposition[J].Diamond and Related Materials,2002,1 l(3/6):467-471. |
[8] | Fiiner M;Wild C;Koidl P .Novel Microwave Plasma Reactor ior Diamond Synthesis[J].Applied Ph:ics Letters,1998,72(10):1149-1151. |
[9] | F Silva;K Hassouni;X Bonnin;A Gicquel .Microwave engineering of plasma-assisted CVD reactors for diamond deposition[J].Journal of Physics. Condensed Matter,2009(36):364202-16. |
[10] | 王建军;吕反修;邬钦崇 .用发射天线式微波等离子体CVD装置沉积大面积金刚石薄膜[J].高技术通讯,1994,4(11):14-16. |
[11] | 吕庆敖;邬钦崇;隋毅峰 .新型微波等离子体化学气相沉积金刚石薄膜装置[J].真空与低温,1998,4(01):35-37. |
[12] | 李博,韩柏,吕宪义,李红东,汪剑波,金曾孙.微波PCVD法大尺寸透明自支撑金刚石膜的制备及红外透过率[J].新型炭材料,2008(03):245-249. |
[13] | 吴小国,熊瑛,杨保和,李翠平,孙大智,李晓伟.金刚石/硅复合膜的导热特性研究[J].光电子·激光,2007(08):963-965. |
[14] | DingM Q;Li L L;Bai G D.A Study of Free Standing Diamond Films for mm TWTs[A].Bangalore,India,2011:387-388. |
[15] | WANG Feng-ying,郭会斌,TANG Wei-zhong,吕反修.圆柱形和椭球形谐振腔式MPCVD装置中微波等离子体分布特征的数值模拟与比较[J].人工晶体学报,2008(04):895-900,907. |
[16] | 于盛旺,范朋伟,李义锋,刘艳青,唐伟忠.椭球谐振腔式MPCVD装置高功率下大面积金刚石膜的沉积[J].人工晶体学报,2011(05):1145-1149. |
[17] | X.J. Li;W.Z. Tang;S.W. Yu .Design of novel plasma reactor for diamond film deposition[J].Diamond and Related Materials,2011(4):480-484. |
[18] | 于盛旺,李晓静,张思凯,范朋伟,黑鸿君,唐伟忠,吕反修.新型MPCVD装置在高功率密度下高速沉积金刚石膜[J].功能材料,2011(09):1722-1726. |
[19] | 于盛旺;黑鸿君;刘艳青.高功率MPCVD金刚石膜红外光学材料制备研究[J].激光与红外 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%