采用X射线衍射(XRD)法分析了TiCr1.8-xVx储氢合金氢化并吸氢后的相组成,首次采用热重-差热扫描-质谱(TG-DSC-MS)联用技术对合金随温度变化时的放氢特性及所释放氢的状态进行了研究.根据不同升温速率条件下,合金放氢的DSC测试计算了放氢反应的活化能.
参考文献
| [1] | Huang Taizhong;Wu Zhu;Xia Baojia;Xu Naixin .Influence of stoichiometry and alloying elements on the crystallography and hydrogen sorption properties of TiCr based alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):284-287. |
| [2] | Yeh M T;Beibutian V M;Hsu S E.[J].Journal of Alloys and Compounds,1999(293-295):721. |
| [3] | 工作仲;吴铸;徐乃欣 .[J].中国有色金属学报,2006,16(11):1855. |
| [4] | 黄太仲,吴铸,冯尚龙,陈金舟,夏保佳,徐乃欣.V取代TiCr基储氢合金中部分Cr对储氢性能的影响[J].中国有色金属学报,2005(01):141-144. |
| [5] | Santos DSD;Bououdina M;Fruchart D .[J].Journal of Alloys and Compounds,2002,340:101. |
| [6] | Takuya Tamura;Takashi Kazumi;Atsunori Kamegawa .Protium absorption properties and protide formations of Ti-Cr-V alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(0):505-509. |
| [7] | Xinhua Wang;Rugan Chen;Yan Zhang et al.[J].Journal of Alloys and Compounds,2006,420(1-2):322. |
| [8] | Klyamkin S N;Kovriga A Y;Verbetsky V N .[J].International Journal of Hydrogen Energy,1999,24:149. |
| [9] | Sung-Wook Cho;Hirotoshi Enoki;Toshiki Kabutomori .Isotope effect on structural transitions of Ti_(1.0)Mn_(0.9)V_(1.1)H_X(D_X) and Ti_(1.0)Cr_(1.5)V_(1.7)H_X(D_X) with hydrogenation[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(1/2):196-203. |
| [10] | Mouri T.;Iba H. .Hydrogen-absorbing alloys with a large capacity for a new energy carrier[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2002(0):346-350. |
| [11] | Takeo Ozawa .[J].Thermochimica Acta,2000,356:173. |
| [12] | John J R;Sanders P;Patrick Gallagher K .[J].Thermochimica Acta,2002,388:115. |
| [13] | 陆昌伟;奚同庚.热分析质谱法[M].Shanghai:Shanghai Science and Technology Documentary Press,2002:40. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%