采用双(3-三乙氧基甲硅烷基丙基)胺和乙烯基三乙酰氧基硅烷的混合体系,对冷轧钢表面进行硅烷化处理,通过监测硅烷水解液在不同水解时间的pH值和电导率,研究其稳定性能,并研究了硅烷含量和水解溶剂中乙醇的含量对所制备硅烷膜耐腐蚀性能的影响.结果表明:混合硅烷体系的水解液具有较好的稳定性;当混合硅烷含量为2%,水解溶剂中乙醇含量为20%时,所制备硅烷膜具有较好的耐腐蚀性能,且满足工业应用要求.
参考文献
[1] | Zhu DQ.;van Ooij WJ. .Corrosion protection of metals by water-based silane mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane [Review][J].Progress in Organic Coatings: An International Review Journal,2004(1):42-53. |
[2] | Graeve I;Vereecken J;Franquet A;Van Schaftinghen T;Terryn H .Silane coating of metal substrates: Complementary use of electrochemical, optical and thermal analysis for the evaluation of film properties[J].Progress in Organic Coatings: An International Review Journal,2007(3):224-229. |
[3] | 曾恩,张三平,周学杰,郑俊涛,周婵.热镀锌板表面硅烷处理耐蚀性能的研究[J].装备环境工程,2010(01):22-25. |
[4] | M. Pantoja;B. Diaz-Benito;F. Velasco;J. Abenojar;J.C. del Real .Analysis Of Hydrolysis Process Of γ-methacryloxypropyltrimethoxysilane And Its Influence On The Formation Of Silane Coatings On 6063 Aluminum Alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(12):6386-6390. |
[5] | Harun MK.;Lyon SB.;Marsh J. .A surface analytical study of functionalised mild steel for adhesion promotion of organic coatings [Review][J].Progress in Organic Coatings: An International Review Journal,2003(1):21-27. |
[6] | F. Deflorian;S. Rossi;L. Fedrizzi .Silane pre-treatments on copper and aluminium[J].Electrochimica Acta,2006(27):6097-6103. |
[7] | Trabelsi W;Triki E;Dhouibi L;Ferreira MGS;Zheludkevich ML;Montemor MF .The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanised steel substrates[J].Surface & Coatings Technology,2006(14/15):4240-4250. |
[8] | 王雪明 .硅烷偶联剂在金属预处理及有机涂层中的应用研究[D].山东大学,2005. |
[9] | 王雪明,李爱菊,李国丽,管从胜.硅烷偶联剂在防腐涂层金属预处理中的应用研究[J].材料科学与工程学报,2005(01):146-150. |
[10] | 王雪明,李爱菊,李国丽,王威强,赵永辉.金属表面制备KH-560硅烷膜涂层的工艺研究[J].中国表面工程,2004(06):27-31. |
[11] | 王名浩 .水基硅烷化处理剂的制备及应用研究[D].湖南大学,2010. |
[12] | Suegama PH;de Melo HG;Recco AAC;Tschiptschin AP;Aoki IV .Corrosion behavior of carbon steel protected with single and bi-layer of silane films filled with silica nanoparticles[J].Surface & Coatings Technology,2008(13):2850-2858. |
[13] | 谢国先,邱大健,李朝阳,肖祥定.氨基硅烷偶联剂对环氧涂层附着力的影响[J].材料保护,2008(03):22-24. |
[14] | 徐溢,唐守渊,滕毅,张晓凤.金属表面处理用硅烷试剂的水解与缩聚[J].重庆大学学报(自然科学版),2002(10):72-74. |
[15] | Tammy Metroke;Yimin Wang;Wim J. van Ooij .Chemistry of mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane: an NMR analysis[J].Journal of Sol-Gel Science and Technology,2009(1):23-31. |
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