The subsolidus phase relations of the systems K2O-ZnO-AO(3) (A= Mo, W) have been investigated by X-ray diffraction (XRD) analyses. The phase diagrams have been constructed. There are six binary compounds and two ternary compounds in the K2O-ZnO-MoO3 system, it can be divided into 11 three-phase regions. The K2O-ZnO-WO3 system consists of six binary compounds and one ternary compound. This system can be divided into 9 three-phase regions. DTA results indicated the compounds K2MOO4 and K2WO4 are not suitable to be fluxes for ZnO crystal growth. (c) 2006 Elsevier B.V. All rights reserved.
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