通过机械分散技术制备了纳米Al2O3/环氧、酚酞聚芳醚酮/环氧和纳米Al2O3/酚酞聚芳醚酮/环氧复合材料,并对比研究了其拉伸模量、拉伸强度、断裂性能和热性能.结果表明:纳米Al2O3及酚酞聚芳醚酮在环氧树脂中呈均匀的分散状态;纳米Al2O3使环氧树脂拉伸模量增加,使拉伸强度先增后降;酚酞聚芳醚酮使环氧树脂拉伸模量略微下降,对拉伸强度影响不明显;纳米Al2O3/酚酞聚芳醚酮/环氧三元复配体系的拉伸模量和拉伸强度呈非单调变化的趋势;纳米Al2O3和酚酞聚芳醚酮对环氧树脂均有增韧作用,三元复配体系增韧效果更明显,表现出协同增韧效果;高含量纳米Al2O3降低了环氧树脂的初始分解温度,而其余填料对环氧树脂热稳定性具有改善作用,填料均使环氧树脂玻璃化转变温度有所降低.
参考文献
[1] | Zunjarrao S C,Singh R P.Characterization of the fracture behavior of epoxy reinforced with nanometer and micrometer sized aluminum particles[J].Composites Science and Tech nology,2006,66(13):2296-2305.,2006. |
[2] | Mirmohseni A,Zavareh S.Preparation and characterization of an epoxy nanocomposite toughened by a combination of thermoplastic,layered and particulate nano fillers[J].Ma terials & Design,2010,31(6):2699-2706.,2010. |
[3] | Liu H Y,WangGT,MaiYW,etal.On fracture toughness of nano particle modified epoxy[J].Composites Part B:En gineering,2011,42(8):2170-2175.,2011. |
[4] | Chikhi N,Fellahi S,Bakar M.Modification of epoxy resin u sing reactive liquid (ATBN) rubber[J].European Polymer Journal,2002,38(2):251-264.,2002. |
[5] | Wu H,Xu J,Liu Y,et al.Investigation of readily proces sable thermoplastic toughened thermosets.V.epoxy resin toughened with hyperbranched polyester[J].Journal of Ap plied Polymer Science,1998,72(2):151-163.,1998. |
[6] | Jang J,Shin S.Toughness improvement of tetrafunctional epoxy resin by using hydrolysed poly (ether imide)[J].Pol ymer,1995,36(6):1199-1207.,1995. |
[7] | Kinloch A J,Yuen M L,Jenkins S D.Thermoplastic tough ened epoxy polymers[J].Journal of Materials Science,1994,29(14):3781-3790.,1994. |
[8] | Dong Y,Chaudhary D,Ploumis C,et al.Correlation of me chanical performance and morphological structures of epoxy micro/nanoparticulate composites[J].Composites Part A:Applied Science and Manufacturing,2011,42(10):1483-1492.,2011. |
[9] | Omrani A,Simon L C,Rostami A A.The effects of alumina nanoparticle on the properties of an epoxy resin system[J].Materials Chemistry and Physics,2009,114(1):145-150.,2009. |
[10] | 郑亚萍,王波.TiO2/环氧树脂纳米复合材料的研究[J].复合材料学报,2002(04):11-13. |
[11] | Liang Y L,Pearson R A.The toughening mechanism in hy brid epoxy-silica-rubber nanocomposites (HESRNs)[J].Polymer,2010,51(21):4880-4890.,2010. |
[12] | Chen C,Justice R S,Schaefer D W,et al.Highly dispersed nanosilica epoxy resins with enhanced mechanical properties[J].Polymer,2008,49(17):3805-3815.,2008. |
[13] | American Society for Testing and Materials.ASTM D 638-03 Standard test method for tensile properties of plastics[S].West Conshohocken,United States:ASTM International,2003.,2003. |
[14] | American Society for Testing and Materials.ASTM D5045-99 Standard test methods for plane strain fracture toughness and strain energy release rate of plastic materials[S].West Conshohocken,United States:ASTM International,2003.,2003. |
[15] | WetzelB,RossoP,Haupert F,et al.Epoxynanocomposites fracture and toughening mechanisms[J].Engineering Frac ture Mechanics,2006,73(16):2375-2398.,2006. |
[16] | LimSH,ZengKY,HeCB.Morphology,tensile and frac ture characteristics of epoxy-alumina nanocomposites[J].Materials Science and Engineering:A,2010,527(21-22):5670-5676.,2010. |
[17] | Shukla D K,Kasisomayajula S V,Parameswaran V.Epoxy composites using functionalized alumina platelets as reinforce ments[J].Composites Science and Technology,2008,68(14):3055-3063.,2008. |
[18] | Wetzel B,Haupert F,Qiu Zhang M.Epoxy nanocomposites with high mechanical and tribological performance[J].Com posites Science and Technology,2003,63(14):2055-2067.,2003. |
[19] | Johnsen B B,Kinloch A J,Mohammed R D,et al.Toughe ning mechanisms of nanoparticle modified epoxy polymers[J].Polymer,2007,48(2):530-541.,2007. |
[20] | Zhao S,Schadler L,Duncan R,et al.Mechanisms leading to improved mechanical performance in nanoscale alumina filled epoxy[J].Composites Science and Technology,2008,68(14):2965-2975.,2008. |
[21] | Zhao S,Schadler L,Hillborg H,et al.Improvements and mechanisms of fracture and fatigue properties of well dispers ed alumina/epoxy nanocomposites[J].Composites Science and Technology,2008,68(14):2976-2982.,2008. |
[22] | Liu G,Zhang H,Zhang D J,et al.On depression of glass transition temperature of epoxy nanocomposites[J].Journal of Materials Science,2012,47(19):6891-6895.,2012. |
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