对TiO2光催化剂进行改性,实现可见光催化活性是第二代光催化剂走向实用化的关键.氮掺杂TiO2是一种理想的具有可见光活性的光催化剂,由于N 2p态与O 2p态杂化,实现带隙窄化和吸收带边红移,对于实现可见光催化活性具有重要意义.评述了氮掺杂改性TiO2光催化剂的国内外研究现状,分析了不同掺杂方法对于实现TiO2可见光催化活性的掺杂机理和改性机理,提出研究合适的催化剂载体对TiO2进行氮等非金属负载是今后努力的方向,并且应该建立统一的催化剂性能评价标准.
参考文献
[1] | 彭峰,黄垒,陈水辉.非金属掺杂的第二代二氧化钛光催化剂研究进展[J].现代化工,2006(02):18-22. |
[2] | Clemens Burda;Yongbing Lou;Xiaobo Chen;Anna C. S. Samia;John Stout;James L. Gole .Enhanced Nitrogen Doping in TiO_2 Nanoparticles[J].Nano letters,2003(8):1049-1051. |
[3] | Asahi R et al.Visible-light photocatalysis in nitrogendoped titanium oxides[J].Science,2001,293:269. |
[4] | K. Prabakar;T. Takahashi;T. Nezuka;T. Nakashima;Y. Kubota;A. Fujishima .Effect of nitrogen on the photocatalytic activity of TiO_(x)N_(y) thin films[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,2006(4):1156-1160. |
[5] | Maeda M;Watanabe T .Visible light photocatalysis of nitrogen-doped titanium oxide films prepared by plasma-enhanced chem vapor deposition[J].Journal of the Electrochemical Society,2006,153(03):186. |
[6] | Guo Y;Zhang X W;Han G R .Investigation of structure and properties of N-doped TiO2 thin films grown by APCVD[J].Materials Science and Engineering B,2006,135:83. |
[7] | Yates H M et al.The role of nitrogen doping on the development of visible light-induced photocatalytic activity in thin TiO2 films grown on glass by chemical vapour deposition[J].Journal of Photochemistry and Photobiology A:Chemistry,2006,179:213. |
[8] | Sathish M et al.Synthesis,characterization,electronic structure,and photocatalytic activity of nitrogen-doped TiO2 nanocatalyst[J].Chemistry of Materials,2005,17:6349. |
[9] | 熊予莹,费贤翔,熊建文,张镇西.可见光响应掺氮TiO2的制备及对白血病HL60细胞体外杀伤效应的研究[J].稀有金属材料与工程,2006(11):1735-1739. |
[10] | Irie H;Watanabe Y;Hashimoto K .Nitrogen-concentration dependence on photocatalytic activity of TiO2-xNx powders[J].Journal of Physical Chemistry B,2003,107(23):5483. |
[11] | Kosowska B;Mozia S;Morawski AW;Grzmil B;Janus M;Kalucki K .The preparation of TiO2-nitrogen doped by calcination of TiO2 center dot xH(2)O under ammonia atmosphere for visible light photocatalysis[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(3):269-280. |
[12] | Tachikawa T;Takai Y;Tojo S et al.Visible light-induced degradation of ethylene glycol on nitrogen-doped TiO2 powders[J].Journal of Physical Chemistry B,2006,110:13158. |
[13] | Wu PG;Ma CH;Shang JK .Effects of nitrogen doping on optical properties of TiO2 thin films[J].Applied physics, A. Materials science & processing,2005(7):1411-1417. |
[14] | Yamada K;Nakamura H;Matsushima S et al.Preparation of N-doped TiO2 particles by plasma surface modification[J].Comptes Rendus Chimie,2006,9:788. |
[15] | Hong Shen;Lan Mi;Peng Xu;Weidian Shen;Pei-Nan Wang .Visible-light photocatalysis of nitrogen-doped TiO_2 nanoparticulate films prepared by low-energy ion implantation[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(17):7024-7028. |
[16] | Wan L;Li JF;Feng JY;Sun W;Mao ZQ .Improved optical response and photocatalysis for N-doped titanium oxide (TiO2) films prepared by oxidation of TiN[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(10):4764-4767. |
[17] | Gandhe A R;Fernandes J B .A simple method to synthesize N-doped rutile titanium with enhanced photocatalytic activity in sunlight[J].Journal of Solid State Chemistry,2005,178:2953. |
[18] | Yang TS;Yang MC;Shiu CB;Chang WK;Wong MS .Effect of N-2 ion flux on the photocatalysis of nitrogen-doped titanium oxide films by electron-beam evaporation[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(10):3729-3736. |
[19] | Yuan J;Chen M X;Shi J W et al.Preparation and photocatalytic hydrogen evolution of N-doped TiO2 from and titanium tetrachloride[J].International Journal of Hydrogen Energy,2006,31:1326. |
[20] | Yu J G et al.Preparation,characterization and photocatalytic activity of in situ N,S-codoped TiO2 powders[J].Journal of Molecular Catalysis A:Chemical,2006,246:176. |
[21] | Liu H Y;Gao L .(Sulfur,nitrogen)-codoped rutile-titanium dioxide as a visible-light-activited photocatalyst[J].Communications of the American Ceramic Society,2004,87(08):1582. |
[22] | Huang DG;Liao SJ;Liu JM;Dang Z;Petrik L .Preparation of visible-light responsive N-F-codoped TiO2 photocatalyst by a sol-gel-solvothermal method[J].Journal of Photochemistry and Photobiology, A. Chemistry,2006(3):282-288. |
[23] | Pan CC;Wu JCS .Visible-light response Cr-doped TiO2-N-X(X) photocatalysts[J].Materials Chemistry and Physics,2006(1):102-107. |
[24] | Wong MS;Chou HP;Yang TS .Reactively sputtered N-doped titanium oxide films as visible-light photocatalyst[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):244-249. |
[25] | 唐玉朝,黄显怀,俞汉青,胡春.N掺杂TiO2光催化剂的制备及其可见光活性研究[J].无机化学学报,2005(11):1747-1751. |
[26] | Sato S .Photocatalytic activity of NOx-doped TiO2 in the visible light region[J].Chemical Physics Letters,1986,123(1-2):126. |
[27] | Hong YC;Bang CU;Shin DH;Uhm HS .Band gap narrowing of TiO2 by nitrogen doping in atmospheric microwave plasma[J].Chemical Physics Letters,2005(4-6):454-457. |
[28] | Jansen M;Letschert H P .Inorganic yellow-red pigments without toxic metals[J].Nature,2000,404(27):980. |
[29] | Ihara T et al.Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping[J].Appl Catalysis B,2003,42:403. |
[30] | Chu S Z;Inoue S;Wada K et al.Fabrication and photocatalytic characterizations of ordered nanoporous X-doped(X=N,C,S,Ru,Te,and Si) TiO2/Al2O3 films on ITO/glass[J].Langmuir,2005,21:8035. |
[31] | Diwald O;Thompson T L;Zubkov T et al.Photochemical activity of nitrogen-doped rutile TiO2 (110) in visible light[J].Journal of Physical Chemistry B,2004,108:6004. |
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