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通过丝网印刷工艺, 制备了具有高的比表面积的纳米晶氧化钛薄膜, 通过有机/无机复合, 在氧化钛薄膜表面吸附了单层的电变色子, 制备成纳米晶电极并且装配成三明治结构的电致
变色器件. 通过紫外可见分光光度计表征, 该器件的着色态透过率为4%, 退?色态透过率为85%. 其在智能窗、平板显示器、电子书和电子报纸等领域具有潜在的应用前景.

Nanocrystralline TiO2 semiconducting electrode was prepared by using a screen-printing technique. The electrode has very high specific surface-to-volum area which is crucial for the absorption of
more chromophores on the surface. The electrochromic device was assembled by using a sandwich structure after the electrode absorbed chromophore molecules. The electrochromic device was
characterized by UV-Vis spectra. The electrochromic device has a very high transparency at its bleached states (85%), and deep violet at its colored states (4%), which has potential use in smart window, flat
panel display, electric book and electric papers.

参考文献

[1] Monk P M S, Mortimer R J D, Rosseinsky R. Electrochromism, VCH, Weinheim, 1995.
[2] Granqvist C G, Azens A, Hjelm A, Kullman L. Solar Energy, 1998, 63(4): 199-216.
[3] Gratzel M. Nature, 2001, 409: 575-576.
[4] Cummins D, Boschloo G. J. Phys. Chem. B, 2000, 104: 11449-11459.
[5] Linsebigler A L, Lu G Q, John T. Chemical Reviews, 1995, 95(3): 735-758.
[6] O’Reagan B, Gratzel M. Nature, 1991, 353: 737-739.
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