粘土合成的介孔材料(MSCs)是用聚合物或有机物有机改性的粘土凝胶经过水热结晶,然后焙烧脱去有机模板而制得的.介孔半径的大小与聚合物重量百分含量及其分子量大小有关.该类介孔材料可应用于催化剂载体、分子的选择吸收等领域.综述了MSCs的制备方法、表征及其应用等研究进展.
参考文献
[1] | KresgeCT;Leonowicz M E;Roth W J et al.Ordered mesoporous materials by emulsion templating[J].Nature,1992,359:710. |
[2] | eckJS;Vartuli J C;Roth W J et al.[J].Journal of the American Chemical Society,1992,114:10834. |
[3] | 赵芸,李峰,Evans D G,段雪,郝建薇.纳米LDH对环氧树脂燃烧的抑烟作用[J].应用化学,2002(10):954-957. |
[4] | CarradoKA;Marshall C L;Brenne J Rr et al.Materials derived from synthetic organo-clay complexes as novel hydrodesulfurization catalyst supports[J].Microporous and Mesoporous Materials,1998,20:17. |
[5] | K. A. Carrado;Langqiu Xu .Materials with controlled mesoporosity derived from synthetic polyvinylpyrrolidone-clay composites[J].Microporous and Mesoporous Materials,1999(1):87-94. |
[6] | GrimRE.[A].McGraw-Hill NY,1968:68. |
[7] | arrerRM;Dicks L W R.Chemistry of soil minerals: Part Ⅳ Synthetic alkyl-ammonium montmorillonites and hectorites[J].Journal of the Chemical Society,1967:1523. |
[8] | CarradoKA;Thiyagarajan P;Song K .A study of organohectorite clay crystallization[J].Clay Minerals,1997,32:29. |
[9] | CarradoKA;Forman J E;Botto R E et al.[J].Chemistry of Materials,1993,5:472. |
[10] | Carrado-GregarK;Winans R E;Botto R E .Organic or organometallic template mediated clay synthesis[P].US Pat,5,1994. |
[11] | CarradoKA;Thiyagarajan P;Winans R E et al.Hydrothermal crystallization of porphyrin- containing layer silicates[J].Inorganic Chemistry,1991,30:794. |
[12] | CarradoKA;Thiyagarajan P;Elder D L .Polyvinyl alcoholclay complexes formed bydirect synthesis[J].Clays and Clay Minerals,1996,44:506. |
[13] | Carrado KA.;Song K.;Brenner JR.;Zajac GW. .CRYSTAL GROWTH OF ORGANOHECTORITE CLAY AS REVEALED BY ATOMIC FORCE MICROSCOPY[J].Langmuir: The ACS Journal of Surfaces and Colloids,1997(10):2895-2902. |
[14] | CarradoKA;Thiyagarajan P;Elder D L.Porous networks derived from synthetic polymer-clay complexes[A].Marcel Dekker NY,1997:551. |
[15] | Carrado KA.;Xu LQ. .In situ synthesis of polymer-clay nanocomposites from silicate gels[J].Chemistry of Materials,1998(5):1440-1445. |
[16] | KloproggeJT;Komarneni S;Amonette J E .Synthesis of smectite clay minerals: a critical review[J].Clays and Clay Minerals,1999,47:529. |
[17] | Rosa-russinMF .The use of clays for the hydrotreatment of heavy crude oils[J].Catalysis Review-Science and Engineering,1995,37:1. |
[18] | Hensen EJM.;Debeer VHJ.;Vanveen JAR.;Vansanten RA.;Vissenberg MJ. .KINETICS AND MECHANISM OF THIOPHENE HYDRODESULFURIZATION OVER CARBON-SUPPORTED TRANSITION METAL SULFIDES[J].Journal of Catalysis,1996(2):429-435. |
[19] | VasudevanPT;Fierro J L G .A review of deep hydrodesulfurization catalysis[J].Catalysis Review-Science and Engineering,1996,38:161. |
[20] | CarradoKA;Xu L;Marshall C L.Mesoporous synthetic clays: synthesis, characterization, and use as HDS catalyst supports[M].Elsevier,2000 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%