采用常规的陶瓷工艺制备了BaWO4/(Ba,Sr)TiO3复合陶瓷,并通过X射线衍射、扫描电镜及介电性能测试对陶瓷的烧结特性、微结构和介电性能进行了研究.结果表明,BaWO4/(Ba,Sr)TiO3复合陶瓷在1250~1300℃可以实现致密化烧结,且陶瓷由(Ba,Sr)TiO3和BaWO4两相复合而成,未检测到其它物相.随着BaWO4含量的增加,材料的表观密度逐渐增大,介电常数和可调度逐渐降低,介电损耗变化不大,均在10-3量级.典型样品(60%BaWO4/40 0ABa0.5Sr0.5TiO3,质量分数)介电常数182.7,介电损耗0.0024,在2 V·μm-1偏置电场下的可调度为14.7%,具有较好的介电性能.
参考文献
[1] | Syamaprassd U,Galgali R K,Mohanty B C.Dielectric properties of the Bal-xSrxTiO3 system[J].Materials Letters,1988,7:197-200. |
[2] | Herner S B,Sclmi F A,Varadan V V,Varadan V K.The effect of various dopants on the dielectric properties of barium strontium titanate[J].Materials Letters,1993,15:317-324. |
[3] | Diamond H.Variation of permittivity with electric field in perovskite-like ferroelectrics[J].Journal of Applied Physics,1961,32:909-915. |
[4] | Zhai J W,Yao X,Cheng X G,et al.Dielectric properties under DC-bias field of Ba0.6Sr0.4TiO3 with various grain sizes[J].Materials Science and Engineering,2002,B94:164-169. |
[5] | Zhai J W,Yao X,Cheng X G,et al.Direct-current field dependence of dielectric properties in B2O3-SiO2 glass doped ceramics[J].Journal of Materials Science,2002,37:3739-3745. |
[6] | Chang Wontae,Sengupta Louise.MgO-mixed Ba0.4Sr0.4TiO3 bulk ceramics and thin films for tunable microwave applications[J].Journal of Applied Physics,2002,92(7):3941-3946. |
[7] | Sengupta L C,Sengupta S.Breakthrough advances in low loss tunable dielectric materials[J].Materials Research Innovations,1999,2:278-282. |
[8] | 高峰,杨祖培,刘向春,田长生.铁电陶瓷/铁氧体复合材料的相结构与介电性能[J].复合材料学报,2004,21(5):22-27.Gao Feng,Yang gupei,Liu Xiangchun,Tian Changsheng.Phase structure and dielectric properties of ferroeleetrics and ferrite mixed composites[J].Acta Materiae Compositae Sinica,2004,21(5):22-27. |
[9] | Sengupta Louise,Ngo Eric,Stowell Steven,et al.Ceramic ferroelectric material:United States,5312790[P].1994-05-17. |
[10] | Sengupta Louise,Ngo Eric,Stowell Steven,et al.Ceramic ferroelectric composite material-BSTO-MgO:United States,5427988[P].1995-06-27. |
[11] | Sengupta Louise,Ngo Eric,Stowelt Steven,et al.Ceramic ferroelectric composite material-BSTO-ZrO2:United States,5486491[P].1996-01-23. |
[12] | Sengupta Louise.Ceramic ferroelectric composite materialBSTO-ZnO:United States,5635433[P].1997-06-03. |
[13] | Sengupta Louise.Ceramic ferroelectric composite materialBSTO-magnesium based compound:United States,5635434[P].1997-06-03. |
[14] | Chiu Luna H,Zhang Xubai,Sengupta Louise.Electronically tunable ceramic materials including tunable dielectric and metal silicate phases:United States,6514895[P].2003-02-04. |
[15] | 孙建英,翟继卫,丑修建,姚熹.Ba0.6Sr0.4TiO3-Mg2TiO4复合陶瓷材料的介电可调性及微波特性[J].硅酸盐学报,2007,35(11):1415-1418.Sun Jianying,Zhai Jiwei,Chou Xiujian,Yap Xi.Tunability and microwave properties of Ba0.6Sr0.4 TiO3-Mg2 TiP4 composite ceramics[J].Journal of the Chinese Ceramic Society,2007,35(11):1415-1418. |
[16] | Tian Zhongqing,Liu Hangxing,Yu Hongtao,Ouyang Shixi.Effect of BaWO4 on microstrncture microwave dielectric properties of Ba(Mg1/3 Nb2/3)O2[J].Materials Chemistry and Physics,2004,86:228-232. |
[17] | Nishigaki Susumu,Yano Shinsuke,Kato Hiroshi,et al.BaO -TiO2-WO3 microwave ceramics and crystalline BaWO4[J].Journal of American Ceramic Society,1988,71(1):C11-C17. |
[18] | Sengupta L C,Sengupta S.Novel ferroelectric materials for phased array antennas[J].IEEE Trans Uhrason Ferroelectr Frequency Control,1997,44:792-797. |
[19] | Chen Ying,Dong Xianlin.Dielectric properties of Ba0.6Sr0.4-TiO3/Mg2SiO4/MgO composite ceramics[J].Journal of Applied Physics,2005,98:1-5. |
[20] | Su B,Button T W.Microstructure and dielectric properties of Mg-doped barium strontium titanate ceramics[J].Journal of Applied Physics,2004,95:1382-1385. |
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