以硅藻土和凹凸棒石粘土为原料,烧结硅藻土/凹凸棒石多孔陶器。采用X射线衍射分析( XRD)和扫描电镜( SEM)等手段对样品进行表征,并从吸附亚甲基蓝性能评估材料对印染废水的吸附性能。结果表明:硅藻土和凹凸棒石粘土质量比为20∶80,850℃烧结得到样品保留有硅藻土多孔构造,凹凸棒石相转变为顽火辉石相;样品吸水率为41.12%,抗折强度为2.76 MPa以及收缩率为4.95%。对亚甲基蓝溶液吸附实验表明:样品对亚甲基蓝溶液有较好吸附效果,吸附量为3.634 mg/g。
Diatomite and palygorskite porous ceramics were prepared from diatomite and palygorskite by sintering method .The structures and micrographs of specimens were characterized by X-ray diffraction ( XRD ) and scanning electron microscopy ( SEM ) . The ability of adsorption dye wastewater was measured by adsorptions of methylene blue from aqueous solution .The results of experiment show that diatomite/palygorskite porous ceramics was prepared from diatomite and palygorskite of mass ratio was 20∶80 and sintered at 850 ℃has optimal performance , it water adsorption was 41.12%, flexural strength was 2.76 MPa and shrink rate was 4.95%.Some porous structure of diatomite were retained , the phase of enstatite has been transformed from palygorskite .The phenomenons of adsorption experiment show that sample had better adsorption effect of methylene blue solution and adsorbed amount was 3.634 mg/g.
参考文献
[1] | Zhao, Pin;Gao, Baoyu;Yue, Qinyan;Kong, Jiaojiao;Shon, Ho Kyong;Liu, Pan;Gao, Yuan.Explore the forward osmosis performance using hydrolyzed polyacrylamide as draw solute for dye wastewater reclamation in the long-term process[J].Chemical engineering journal,2015:316-324. |
[2] | Xin Zhuang;Ying Wan;Cuimiao Feng.Highly Efficient Adsorption of Bulky Dye Molecules in Wastewater on Ordered Mesoporous Carbons[J].Chemistry of Materials: A Publication of the American Chemistry Society,20094(4):706-716. |
[3] | Runping Han;Jingjing Zhang;Pan Han.Study of equilibrium,kinetic and thermodynamic parameters about methylene blue adsorption onto natural zeolite[J].Chemical engineering journal,20093(3):496-504. |
[4] | Gholamreza Kiani;Mohammad Dostali;Ali Rostami;Ali R. Khataee.Adsorption studies on the removal of Malachite Green from aqueous solutions onto halloysite nanotubes[J].Applied clay science,20111(1):34-39. |
[5] | 匡猛;王平;彭虎;韦仲华;韦宇洪;李呈权;谢亮.热闭系法甲酸提纯硅藻土研究[J].硅酸盐通报,2015(12):3626-3629. |
[6] | 高如琴;郑水林;刘月;许辉;王彩丽.硅藻土基多孔陶瓷的制备及其对孔雀石绿的吸附和降解[J].硅酸盐学报,2008(1):21-24,29. |
[7] | 郝佳瑞;贾旭宏;严春杰.硅藻土/高岭土复合多孔陶瓷的制备[J].非金属矿,2009(6):26-29. |
[8] | 郑水林;王利剑;舒锋;陈俊涛.酸浸和焙烧对硅藻土性能的影响[J].硅酸盐学报,2006(11):1382-1386. |
[9] | 谢晶晶;陈天虎;庆承松;邢波波.热处理凹凸棒石的结构演化[J].地学前缘,2014(5):338-345. |
[10] | Dong, K.;Qiu, F.;Guo, X.;Xu, J.;Yang, D.;He, K..Polyurethane-attapulgite porous material: Preparation, characterization, and application for dye adsorption[J].Journal of Applied Polymer Science,20134(4):1697-1706. |
[11] | J. X. Lin;S. L. Zhan;M. H. Fang;X. Q. Qian.The adsorption of dyes from aqueous solution using diatomite[J].Journal of porous materials,20074(4):449-455. |
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