分析了钒系催化剂3种制备方法的优缺点.综述了钒系催化剂发展现状及其在工业生产中的应用领域.如硫酸生产、烟气脱硫脱氮处理、苯酐生产、顺酐生产、催化聚合、烷基化反应、氧化脱氢反应等.重点介绍了硫酸生产用钒催化剂的研究与应用现状、存在的主要问题及发展趋势.最后展望了钒系催化剂的发展动向.
参考文献
| [1] | 孙锦宜.工业催化剂的失活与再生[M].北京:化学工业出版社,2006 |
| [2] | 王金超,陈厚生,吴健春,杨绍利.纳米V2O5催化剂的开发[J].钢铁钒钛,2002(04):10-13. |
| [3] | P(a)rvulescu V I;Paun C et al.Vanadia-silica and vanadiacesium-silica catalysts for oxidation of SO2[J].Journal of Catalysis,2004,225:24. |
| [4] | 李国东.SO2氧化制酸催化剂的选型及装填[J].化学与生物工程,2005(03):52-54. |
| [5] | 王尚弟;孙俊全.催化工程导论[M].北京:化学工业出版社,2007 |
| [6] | Karl H. Daum,茆卫兵.应对高浓度SO2烟气的挑战[J].硫酸工业,2006(01):1-10. |
| [7] | Paun C;Massiot P;Grange P et al.New vanadia-mesoporous catalysts for the oxidation of SO2 in diluted gases[J].Catalysis Today,2004,91:33. |
| [8] | 马育新,吕晓华.铯钒硫酸催化剂的研制[J].新疆有色金属,2003(04):29-31. |
| [9] | 康喆,姜龙蛟.新型低温钒催化剂S112的研制[J].硫酸工业,2004(06):43-46. |
| [10] | 高家诚,陈功明,杨绍利,徐楚韶,王勇.含纳米V2O5颗粒钒催化剂的制备[J].稀有金属材料与工程,2004(04):439-441. |
| [11] | Jiang W;Liang B .Fabrication of structured vanadium catalyst for SO2 conversion[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):1-7. |
| [12] | 田先国,张秋菊,丁建芳,陈雷.高性能钒催化剂的研制[J].硫酸工业,2004(02):22-24. |
| [13] | Kim M I et al.Selective oxidation of hydrogen sulfide containing excess water and ammonia over vanadia-titania aerogel catalysts[J].Catalysis Today,2006,111:212. |
| [14] | Park D W;Park B K;Woo H C et al.Vanadium-antimony mixed oxide catalysts for the selective oxidation of H2S containing excess water and ammonia[J].Applied Catalysis A:General,2002,233:215. |
| [15] | Sena Yasyerli;Gulsen Dogu;Timur Dogu .Selective oxidation of H_2S to elemental sulfur over Ce-V mixed oxide and CeO_2 catalysts prepared by the complexation technique[J].Catalysis Today,2006(1/3):271-278. |
| [16] | 金杏妹.工业应用催化剂[M].上海:华东理工大学出版社,2004 |
| [17] | 马建蓉,刘振宇,郭士杰.同时脱除烟气中硫和硝的V2O5/AC催化剂研究[J].燃料化学学报,2005(01):6-11. |
| [18] | 王艳莉,詹亮,凌立成,刘振宇.载钒量对蜂窝状V2O5/ACH催化剂同时脱硫脱硝活性的影响[J].华东理工大学学报（自然科学版）,2006(05):497-502,534. |
| [19] | 马伟棉.苯酐生产工艺进展[J].河北化工,2006(09):21-22. |
| [20] | 周晓东.BC-239型苯酐催化剂的工业应用[J].精细石油化工进展,2004(07):29-32. |
| [21] | 储伟.催化剂工程[M].成都:四川大学出版社,2006 |
| [22] | Yap Y H;Leong L K;Irmawati R .n-Butane oxidation over γ-Al2O3 supported vanadium phosphate catalysts[J].Journal of Natural Gas Chemistry,2007,16:266. |
| [23] | Yap Y H .Effect of Cr and Co promoters addition on vanadium phosphate catalysts for mild oxidation ofn-butane[J].Journal of Natural Gas Chemistry,2006,15:144. |
| [24] | 金晶,崔华,董颖,王秀芝,廖凤英,陈可佳,邹向阳,蔡小平.新型钒催化剂用于催化乙烯-丙烯共聚合的研究[J].弹性体,2004(05):58-60. |
| [25] | 吉拉 L .钒基催化剂及其用途[P].CN 1165141,1997-11-19. |
| [26] | LIU Yu,夏少武,钟永军.Ziegler-Natta型钒系催化剂相态的研究[J].青岛化工学院学报(自然科学版),2001(01):12-15. |
| [27] | 许学翔,程薇,宗明生,纪洪波,时晓岚,景振华.负载型二（2-乙酰基-1-萘酚氧基）二氯化钒催化剂的制备及其催化乙烯聚合反应[J].石油化工,2007(03):242-247. |
| [28] | 李文英,李晓红,宋瑞伟.钒/钛复合氧化物催化剂用于二氧化碳气氛中乙苯氧化脱氢[J].催化学报,2006(12):1117-1121. |
| [29] | 张赪,余少兵,郝小明,宗保宁.乙苯氧化脱氢制苯乙烯催化剂[J].化工进展,2006(11):1354-1357. |
| [30] | 胡虹,孟璇,施力.铌改性V2O5催化甲醇乙醇一步合成异丁醛催化剂的催化性能研究[J].天然气化工,2007(04):1-4,15. |
| [31] | Wimonrat TRAKARNPRUK,Piyanoot HOONSART.醇在钒基催化剂上的氧化[J].催化学报,2007(04):290-292. |
| [32] | Reddy B M;Ratnam K J;Saikia P et al.Influence of alkaline earth metal on acid-base characteristics of V2O5/MOTiO2(M=Ca,Sr and Ba)catalysts[J].Appl Cataly A:Chemical,2007,276:197. |
| [33] | Xue M W;Ge J Z;Zhang H L et al.Surface acidic and redox properties of V-Ag-Ni-O catalysts for the selective oxidantion of toluene to benzaldehyde[J].Applied Catalysis A:General,2007,330:117. |
| [34] | Pombeiro et al.Process for direct conversion of methane into acetic acid[P].US 7238838,2007-07-03. |
| [35] | Gu Y Y;Zhao X H;Zhang G R et al.Selective hydroxylation of benzene using dioxygen activated by vanadium-copper oxide catalysts supported on SBA-15[J].Applied Catalysis A:General,2007,328:150. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%