简要综述了近年来用于光催化还原CO<,2>的TiO<,2>材料,包括单- TiO<,2>光催化材料、金属负载型TiO<2>材料、半导体复合TiO<,2>光催化材料、有机光敏化剂修饰TiO<,2>光催化材料、TiO<,2>分子筛光催化材料及其他TiO<,2>光催化材料,总结了各种TiO<,2>材料光催化CO<,2>的优势,并介绍了其相应的光催化反应机理.
参考文献
| [1] | Bernstein L;Pachauri R K;Reisinger A.Climate change 2007:Synthesis report[A].Geneva,Switzerland:IPCC,2007:104. |
| [2] | 许阳,毛玉如.能源洁净利用与CO2排放控制技术[J].能源工程,2002(04):11-15. |
| [3] | Phairat Usubharatana;Dena McMartin;Amornvadee Veawab;Paitoon Tontiwachwuthikul .Photocatalytic Process for CO_2 Emission Reduction from Industrial Flue Gas Streams[J].Industrial & Engineering Chemistry Research,2006(8):2558-2568. |
| [4] | Cosa G.;Galletero MS.;Fernandez L.;Marquez F.;Garcia H.;Scaiano JC. .Tuning the photocatalytic activity of titanium dioxide by encapsulation inside zeolites exemplified by the cases of thianthrene photooxygenation and horseradish peroxidase photodeactivation[J].New Journal of Chemistry,2002(10):1448-1455. |
| [5] | 余灯华,廖世军,江国东.几种新型光催化剂及其研究进展[J].工业催化,2003(06):48-52. |
| [6] | Hirose T;Maeno Y;Himeda Y .Photocatalytic carbon dioxide photoreduction by Co(bpy)《,3》《'2+》 sensitized by Ru (bpy)《,3》《'2+》 fixed to cation exchange polymer[J].Journal of Molecular Catalysis A:Chemical,2003,193(1-2):27. |
| [7] | 崔俊儒,辛嘉英,牛建中,夏春谷,李树本.甲烷氧化细菌催化二氧化碳生物合成甲醇的研究[J].分子催化,2004(03):214-218. |
| [8] | Lagowski J J.Modern inorganic chemistry[M].New York,USA:Marcel Dekker,Inc,1973:68. |
| [9] | Tanaka K;Miyahara K;Toyoshima I .Adsorption of carbon dioxide on titanium dioxide and platinum/titanium dioxide studied by x-ray photoelectron spectroscopy and Auger electron spectroscopy[J].Journal of Physical Chemistry,1984,88(16):3504. |
| [10] | Varghese OK;Paulose M;LaTempa TJ;Grimes CA .High-Rate Solar Photocatalytic Conversion of CO2 and Water Vapor to Hydrocarbon Fuels[J].Nano letters,2009(2):731-737. |
| [11] | Inoue T;Fujishima A;Konishi S et al.Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders[J].Nature,1979,277(5698):637. |
| [12] | Baiju Vijayan;Nada M. Dimitrijevic;Tijana Rajh .Effect of Calcination Temperature on the Photocatalytic Reduction and Oxidation Processes of H ydrothermally Synthesized Titania Nanotubes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(30):12994-13002. |
| [13] | Yamashita H;Kamada N;He H et al.Reduction of CO《,2》 with H《,2》 O on TiO《,2》 (100) and TiO《,2》 (110) single crystals under UV-irradiation[J].Chemistry Letters,1994,23(05):855. |
| [14] | Koci K;ObalováL;Matějová L et al.Effect of TiO《,2》 particle size on the photocatalytic reduction of CO《,2》[J].Applied Catalysis B:Environmental,2009,89(3-4):494. |
| [15] | Tan S S;Zou L;Hu E .Photocatalytic reduction of carbon dioxide into gaseous hydrocarbon using TiO《,2》 pellets[J].Catalysis Today,2006,115(1-4):269. |
| [16] | Pankaj pathak;Mohammed J.Meziani;Yin Li;Lashonda T.Cureton;Ya-Ping Sun .Improving photoreduction of CO_2 with homogeneously dispersed nanoscale TiO_2 catalysts[J].Chemical communications,2004(10):1234-1235. |
| [17] | Wu J C S;Wu T H;Chu T et al.Application of optical-fiber photoreactor for CO《,2》 photocatalytic reduction[J].Topics in Catalysis,2008,47(3-4):131. |
| [18] | Lo CC;Hung CH;Yuan CS;Wu JF .Photoreduction of carbon dioxide with H-2 and H2O over TiO2 and ZrO2 in a circulated photocatalytic reactor[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(19):1765-1774. |
| [19] | Mizuno T;Adachi K;Ohta K et al.Effect of CO《,2》 pressure on photocatalytic reduction of CO《,2》 using TiO《,2》 in aqueous solutions[J].Journal of Photochemistry and Photobiology A: Chemistry,1996,98(12):8719. |
| [20] | Li Y;Wang W N;Woo M H et al.Photocatalytic reduction of CO《,2》 with H《,2》 O on mesoporous silica supported Cu/ TiO《,2》 catalysts[J].Applied Catalysis B:Environmental,2010,100(1-2):386. |
| [21] | Tseng I H;Wu J C S .Chemical states of metal-loaded titania in the photoreduction of CO《,2》[J].Catalysis Today,2004,97(2-3):113. |
| [22] | Hosna W.Nasution;Ezza Purnama;Soleh Kosela;Jarnuzi Gunlazuardi .Photocatalytic reduction of CO_2 on copper-doped Titania catalysts prepared by improved-impregnation method[J].Catalysis Communications,2005(5):313-319. |
| [23] | Ishitani O;Inoue C;Suzuki Y et al.Photocatalytic reduction of carbon dioxide to methane and acetic acid by an aqueous suspension of metal-deposited TiO《,2》[J].Journal of Photochemistry and Photobiology A: Chemistry,1993,72(03):269. |
| [24] | Zhang Q H;Han W D;Hong Y J et al.Photocatalytic reduction of CO《,2》 with H2 O on Pt-loaded TiO《,2》 catalyst[J].Catalysis Today,2009,148(3-4):335. |
| [25] | Pathak P;Meziani MJ;Castillo L;Sun YP .Metal-coated nanoscale TiO2 catalysts for enhanced CO2 photoreduction[J].Green chemistry,2005(9):667-670. |
| [26] | Koci K;Mateju K;Obalová L et al.Effect of silver doping on the TiO《,2》 for photocatalytic reduction of CO《,2》[J].Applied Catalysis B:Environmental,2010,96(3-4):239. |
| [27] | Xie TF.;Zhu LJ.;Li TJ.;Xu YJ.;Wang DJ. .Application of surface photovoltage technique in photocatalysis studies on modified TiO2 photo-catalysts for photo-reduction of CO2[J].Materials Chemistry and Physics,2001(1):103-106. |
| [28] | Kohno Y;Yamamoto T;Tanaka T et al.Photoenhanced reduction of CO《,2》 by H《,2》 over Rh/TiO《,2》:Characterization of supported Rh species by means of infrared and X-ray absorption spectroscopy[J].Journal of Molecular Catalysis A:Chemical,2001,175(12):173. |
| [29] | Natarajan Sasirekha;Sheikh John;Kannan Shanthi;Sardhar Basha .Photocatalytic performance of Ru doped anatase mounted on silica for reduction of carbon dioxide[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(1/2):169-180. |
| [30] | Amy L. Linsebigler;Guangquan Lu;John T. Yates Jr. .Photocatalysis on TiO_2 Surfaces: Principles, Mechanisms, and Selected Results[J].Chemical Reviews,1995(3):735-758. |
| [31] | 赵春 .Cu/M<,x>O<,y>-TiO<,2>复合效应及其光催化CO<,2>与C<,2>H<,4>合成丙烯酸的研究[D].天津大学,2006. |
| [32] | Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96. |
| [33] | Liu B J;Torimoto T;Yoneyama H .Photocatalytic reduction of carbon dioxide in the presence of nitrate using TiO《,2》 nanocrystal photocatalyst embedded in SiO《,2》 matrices[J].Journal of Photochemistry and Photobiology A: Chemistry,1998,115(03):227. |
| [34] | 刘亚琴,徐耀,李志杰,张秀萍,吴东,孙予罕.CO2在纳米SiO2/TiO2悬浮体系中的光催化还原[J].化学学报,2006(06):453-457. |
| [35] | Nguyen TV;Wu JCS .Photoreduction of CO2 to fuels under sunlight using optical-fiber reactor[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(8):864-872. |
| [36] | 赵春,钟顺和.V2O5-TiO2复合半导体光催化材料结构及光响应性能研究[J].无机化学学报,2006(02):238-242. |
| [37] | 梅长松,钟顺和.Cu/MoO3-TiO2光催化CO2与C3H6反应合成甲基丙烯酸的性能[J].催化学报,2004(12):937-942. |
| [38] | 梅长松 .复合半导体负载金属材料的制备及其光催化CO《,2》和C《,3》 H《,6》反应性能[D].天津:天津大学,2004. |
| [39] | Prashant V. Kamat .Meeting the Clean Energy Demand: Nanostructure Architectures for Solar Energy Conversion[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(7):2834-2860. |
| [40] | Wang C;Thompson R L;Baltrus J et al.Visible light photoreduction of CO《,2》 using CdSe/Pt/TiO《,2》 heterostructured catalysts[J].The Journal of Physical Chemistry Letters,2010,1(01):48. |
| [41] | Clemens Burda;Yongbing Lou;Xiaobo Chen;Anna C. S. Samia;John Stout;James L. Gole .Enhanced Nitrogen Doping in TiO_2 Nanoparticles[J].Nano letters,2003(8):1049-1051. |
| [42] | Ozcan O;Yukruk F;Akkaya EU;Uner D .Dye sensitized artificial photosynthesis in the gas phase over thin and thick TiO2 films under UV and visible light irradiation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(3/4):291-297. |
| [43] | Ozcan O;Yukruk F;Akkaya E U et al.Dye sensitized CO《,2》 reduction over pure and platinized TiO《,2》[J].Topics in Catalysis,2007,44(04):523. |
| [44] | The-Vinh Nguyen;Jeffrey C.S. Wu;Chwei-Huann Chiou .Photoreduction of CO2 over Ruthenium dye-sensitized TiO2-based catalysts under concentrated natural sunlight[J].Catalysis Communications,2008(10):2073-2076. |
| [45] | Jianjun He;Anders Hagfeldt;Sten-Eric Lindquist;Helena Grennberg;Ferenc Korodi;Licheng Sun;Bjorn AKermark .Phthalocyanine-Sensitized Nanostructured TiO_2 Electrodes Prepared by a Novel Anchoring Method[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(9):2743-2747. |
| [46] | 赵志换,范济民,王志忠.温和条件下CoPc/TiO2光催化还原CO2[J].精细化工,2006(01):54-57. |
| [47] | Zhi-Huan Zhao;Ji-Min Fan;Zhi-Zhong Wang .Photo-catalytic CO_2 reduction using sol-gel derived titania-supported zinc-phthalocyanine[J].Journal of cleaner production,2007(18):1894-1897. |
| [48] | Zhao Z H;Fan J M;Liu S H et al.Optimal design and preparation of titania-supported CoPc using sol-gel for the photo-reduction of CO《,2》[J].Chemical Engineering Journal,2009,151(1-3):134. |
| [49] | Heleg V;Willner L.Photocatalysed CO《,2》-fixation to formate and H《,2》-evolution by eosin-modified Pd-TiO《,2》 powders[J].Journal of the Chemical Society,Chemical Communications,1994(18):2113. |
| [50] | Zhang J;Minagawa M;Ayusawa T et al.In situ investigation of the photocatalytic decomposition of NO on the TiHMS under flow and closed reaction systems[J].Journal of Physical Chemistry B,2000,104(48):11501. |
| [51] | Anpo M;Yamashita H;Ichihashi Y et al.Photocatalytic reduction of CO《,2》 with H《,2》 O on titanium oxides anchored within micropores of zeolites:Effects of the structure of the active sites and the addition of Pt[J].Journal of Physical Chemistry B,1997,101(14):2632. |
| [52] | Anpo M;Yamashita H;Ikeue K et al.Photocatalytic reduction of CO《,2》 with H《,2》 O on Ti-MCM-41 and Ti-MCM-48 mesoporous zeolite catalysts[J].Catalysis Today,1998,44(14):327. |
| [53] | Yamashita H;Fujii Y et al.Selective formation of CH《,3》OH in the photocatalytic reduction of CO《,2》 with H《,2》 O on titanium oxides highly dispersed within zeolites and mesoporous molecular sieves[J].Catalysis Today,1998,45(1-4):221. |
| [54] | Ikeue K.;Anpo M.;Yamashita H. .Photocatalytic reduction of CO2 with H2O on titanium oxides prepared within the FSM-16 mesoporous zeolite[J].Chemistry Letters,1999(11):1135-1136. |
| [55] | N.Ulagappan;H.Frei .Mechanistic Study of CO_2 Photoreduction in Ti Silicalite Molecular Sieve by FT-IR Spectroscopy[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2000(33):7834-7839. |
| [56] | Ikeue K;Nozaki S;Ogawa M et al.Photocatalytic reduction of CO《,2》 with H《,2》 O on Ti-containing porous silica thin film photocatalysts[J].Catalysis Letters,2002,80(3-4):111. |
| [57] | Lin W;Han H;Frei H .CO《,2》 Splitting by H《,2》 O to CO and O《,2》 under UV light in TiMCM-41 silicate sieve[J].Journal of Physical Chemistry B,2004,108(47):18269. |
| [58] | Hwang J S;Chang J S;Park S E et al.Photoreduction of carbondioxide on surface functionalized nanoporous catalysts[J].Topics in Catalysis,2005,35(3-4):311. |
| [59] | 樊军;刘恩周;曾波 等.Fe《'3+》掺杂纳米TiO《,2》 催化剂化还原 CO《,2》的性能[J].石油化工,2009,38(07):789. |
| [60] | Ambrus Z;Balázs N;Alapi T et al.Synthesis,structure and photocatalytic properties of Fe(Ⅲ)-doped TiO《,2》 prepared from TiCl3[J].Applied Catalysis B:Environmental,2008,81(1-2):27. |
| [61] | Zhu JF;Chen F;Zhang JL;Chen HJ;Anpo M .Fe3+-TiO2 photocatalysts prepared by combining sol-gel method with hydrothermal treatment and their characterization[J].Journal of Photochemistry and Photobiology, A. Chemistry,2006(1/2):196-204. |
| [62] | Akira Fujishima;Xintong Zhang;Donald A. Tryk .TiO_2 photocatalysis and related surface phenomena[J].Surface Science Reports,2008(12):515-582. |
| [63] | S.Tajammul Hussain,Khaiber Khan,R.Hussain.Size control synthesis of sulfur doped titanium dioxide (anatase) nanoparticles, its optical property and its photo catalytic reactivity for CO_2+H_2O conversion and phenol degradation[J].天然气化学（英文版）,2009(04):383-391. |
| [64] | 罗卓卿,洪崇轩,袁中新,洪雨利.利用TiO2/SO42-光触媒催化还原CO2之参数影响与反应路径探讨[J].催化学报,2007(06):528-534. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%