对纯水体系以及NaCl溶液浓缩过程中真空膜蒸馏传递阻力的分布进行了研究,考察了操作条件对传递阻力分布的影响,分析了传递阻力在浓缩过程的变化原因.结果表明:在纯水体系下,温度和膜表面流速对膜阻力影响较小,其值在162~164.7(Pa·h·m2)/kg范围内变化;边界层阻力受操作条件影响较大,较低的流量和较高的料液温度导致较高的边界层阻力.在NaCl溶液浓缩过程中,渗透通量随浓缩时间起先呈缓慢下降趋势,传递阻力以边界层阻力和膜阻力为主,当料液浓度超过临界值时,渗透通量发生骤降,污染层阻力骤升,膜表面发生结晶污染.但利用清水冲洗受污染膜后,渗透通量恢复率95%左右.因此,控制浓缩终点的浓度低于临界点浓度将有效避免膜污染的形成.
参考文献
[1] | El-Bourawi MS;Ding Z;Ma R;Khayet M .A framework for better understanding membrane distillation separation process[J].Journal of Membrane Science,2006(1/2):4-29. |
[2] | 吕海莉,田瑞,杨晓宏,马淑娟.用于膜蒸馏苦咸水淡化的PTFE疏水膜实验研究[J].膜科学与技术,2012(01):70-74. |
[3] | Grazyna Zakrzewska-Trznadel;Marian Harasimowicz;Andrzej G.Chmielewski .Membrane processes in nuclear technology-application for liquid radioactive waste treatment[J].Separation and Purification Technology,2001(0):617-625. |
[4] | 徐军,李睿,王连军,李建生,孙秀云.真空膜蒸馏分离苯/N-甲酰吗啉水溶液体系微分模型[J].膜科学与技术,2010(05):52-58,63. |
[5] | 王亚飞,张红漫,程丽华,张林,陈欢林.膜蒸馏浓缩纤维素糖液与去除糠醛的研究[J].膜科学与技术,2012(05):92-96. |
[6] | Efrem Curcio;Alessandra Criscuoli;Enrico Drioli .Membrane Crystallizers[J].Industrial & Engineering Chemistry Research,2001(12):2679-2684. |
[7] | Gryta M .Direct contact membrane distillation with crystallization applied to NaCl solutions[J].Chemical Papers,2002,56(01):14-19. |
[8] | 马玖彤,安卫东,张凤君.结晶膜蒸馏回收废水中氯化铵的研究[J].水处理技术,2005(01):26-28. |
[9] | Srisurichan S;Jiraratananon R;Fane AG .Mass transfer mechanisms and transport resistances in direct contact membrane distillation process[J].Journal of Membrane Science,2006(1/2):186-194. |
[10] | Alklaibi AM;Lior N .Heat and mass transfer resistance analysis of membrane distillation[J].Journal of Membrane Science,2006(1/2):362-369. |
[11] | Ding ZW;Liu LY;Yu HF;Ma RY;Yang ZR .Concentrating the extract of traditional Chinese medicine by direct contact membrane distillation[J].Journal of Membrane Science,2008(1/2):539-549. |
[12] | M.Khayet;M.P.Godino;J.I.Mengual .Theoretical and experimental studies on desalination using the sweeping gas membrane distillation method[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2003(1/3):297-305. |
[13] | L.Martinez-Diez;F.J.Florido-Diaz .Desalination of brines by membrane distillation[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2001(1/3):267-273. |
[14] | 贠延滨,马润宇,A G Fane.膜蒸馏污染研究[J].化工新型材料,2004(11):20-22,35. |
[15] | 阎建民,延滨,马润宇.膜蒸馏过程中的膜污染研究[J].膜科学与技术,2001(03):21-23. |
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