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为了研究铁电相BiFeO3对复合薄膜磁性能的影响,在LaNiO3 (LNO)缓冲层的Si(100)衬底上旋涂制备了含有0、6、9、10层等不同厚度BiFeO3的层状CoFe2O4-BiFeO3 (CFO-BFO)多铁复合薄膜.采用XRD、SEM以及TEM对其结构和形貌进行了表征,采用振动样品磁强计测量磁性,研究了不同厚度BFO对复合薄膜磁性的影响.结果表明:CFO和BFO在异质结构薄膜中共存.缓冲层LNO和铁磁相CFO薄膜具有精细微观结构及明显界面.铁电相BFO的厚度对CFO-BFO复合薄膜的磁性能产生了很大影响.在含有不同层数铁电相BFO的复合薄膜中,含有9层BFO复合薄膜的饱和磁化强度最大,达到了230 emu·cm-3,相比无铁电相BFO的薄膜,饱和磁化强度提高了18.6%.初步讨论认为:随着铁电相BFO厚度的增加,CFO与BFO之间的应力传导引起了复合薄膜饱和磁化强度的提高.

参考文献

[1] Yan Li,Yang Yaodong,Wang Zhiguang,Xing Zengping,Li Jiefang,Viehland D.Review of magnetoelectric perovskitespinel self-assembled nano-composite thin films[J].J Mater Sci,2009,44(19):5080-5094.
[2] Ma Jing,Hu Jiamian,Li Zheng,Nan Cewen.Recent progress in multiferroic magnetoelectric composites:From bulk to thin films[J].Adv Mater,2011,23(9):1062-1087.
[3] Lee J H,Fang L,Vlahos E,Ke X L.A strong ferroelectric ferromagnet created by means of spin-lattice coupling[J].Nature,2010,466:954-958.
[4] 于美,胡竞之,刘建华,李松梅.均匀共沉淀法制备BaTiO3-NixZn(1-x)Fe2O4核-壳粒子及其性能[J].高等学校化学学报,2012,33(7):1389-1393.Yu Mei,Hu Jingzhi,Liu Jianhua,Li Songmei.Preparation and characterization of BaTiO3-NixZn1-x Fe2O4 core-shell particles by homogeneous coprecipitation[J].Chemical Journal of Chinese,2012,33(7):1389-1393.
[5] Israel C,Mathur N D,Scott J F.A one-cent roomtemperature magnetoelectric sensor[J].Nat Mater,2008,7:93-94.
[6] Dong S X,Cheng J R,Li J F,Viehland D.Enhanced magnetoelectric effects in laminate composites of Terfenol-D/Pb(Zr,Ti)O3 under resonant drive[J].Appl Phys Lett,2003,83(23):4812-4814.
[7] Ramesh R,Spaldin N.Multiferroics:Progress and prospects in thin films[J].Nat Mater,2007,6:21-29.
[8] Spaldin N A,Fiebig M.The renaissance of magnetoelectric multiferroics[J].Science,2005,309(5733):391-392.
[9] Wang J,Neaton J B,Zheng H,Ramesh R.Epitaxial BiFeO3multiferroic thin film heterostructures[J].Science,2003,299(5613):1719-1722.
[10] Cheong S W,Mostovoy M.Multiferroics:A magnetic twist for ferroelectricity[J].Nat Mater,2007,6:13-20.
[11] 张志力,王哲明,黄云辉,程福祥,廖春生,高松,严纯华.Sol-gel法制备La(1-x)SrxMnO3巨磁电阻薄膜材料[J].高等学校化学学报,1999,20(5):665-669.Zhang Zhili,Wang Zheming,Huang Yunhui,Cheng Fuxiang,Liao Chunsheng,Gao Song,Yan Chunhua.Giant magnetoresistive nanocrystalline films of La1-xSrxMnO3 prepared by sol gel method[J].Chemical Journal of Chinese,1999,20(5):665-669.
[12] Zheng H,Straub F,Zhan Q,et al.Self-assembled growth of BiFeO3-CoFe2O4 nanostructures[J].Adv Mater,2006,18(20):2747-2752.
[13] Zheng H,Wang J,Lofland S E,Ma Z,et al.Multiferroic BaTiO3-CoFe2O4 nanostructures[J].Science,2004,303(5658):661-663.
[14] Curecheriu L P,Buscaglia M T,Buscaglia V,Mitoseriu L,Postolache P,Ianculescu A,Nanni P.Functional properties of BaTiO3-Ni0.5 Zn0.5 Fe2O4 magnetoelectric ceramics prepared from powders with core-shell structure[J].J Appl Phys,2010,107(10):104106 1-104106-11.
[15] Chen W,Shannigrahi S,Chen X F,Wang Z H,Zhu W,Tan O K.Multiferroic behavior and magnetoelectric effect in CoFe2O4/Pb(Zr0.53 Ti0.47) O3 thick films[J].Solid State Commun,2010,150(5/6):271-274.
[16] Zhou Huaiying,Gu Tianlong,Yang Daoguo,Jiang Zhengyi,Zeng Jianmin.Synthesis and characterization of multiferroic NiFe2O4/BiFeO3 nanocomposites by modified pechini method[J].Adv Mat Res,2011,197-198:456-459.
[17] Sim C H,Pan A Z Z,Wang J.Thickness and coupling effects in bilayered multiferroic CoFe2O4/Pb (Zr0.52 Ti0.48) O3 thin films[J].J Appl Phys,2008,103(12):124109-1-124109-7.
[18] He Hongcai,Ma Jing,Lin Yuanhua,Nan Cewen.Enhanced magnetoelectric properties in Pb(Zr,Ti)O3-CoFe2O4 layered thin films with LaNiO3 as a buffer layer[J].J Phys D:Appl Phys,2009,42(9):095008-1-095008-4.
[19] Dix N,Muralidharan R,Rebled J.Seleetable spontaneous polarization direction and magnetic anisotropy in BiFeO3-CoFe2O4 epitaxial nanostructures[J].ACS Nano,2010,4(8):4955-4961.
[20] Dix N,Muralidharan R,Caicedo J M,Hrahovsky D.Influence of substrate temperature in BiFeO3-CoFe2O4nanocomposites deposited on SrTiO3 (001)[J].J Magn Magn Mater,2009,321(11):1790-1794.
[21] Yan L,Wang Z,Xing Z,Li J,Viehland D.Magnetoelectric and multiferroic properties of variously oriented epitaxial BiFeO3-CoFe2O4 nanostructured thin films[J].J Appl Phys,2010,107(6):064106-1-064106-5.
[22] Zheng R Y,Wang J,Ramakrishna S.Electrical and magnetic properties of multiferroic BiFeO3/CoFe2O4 heterostructure[J].J ApplPhys,2008,104(3):034106-1-034106-6.
[23] 钟文定.铁磁学(中册)[M].北京:科学出版社,1998:323-326.Zhong Wending.Ferromagnetism[M].Beijing:Science Press,1998:323-326.
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