对Ag-6Cu-xZn(x=0,1,2)合金铸态显微组织、物相及凝固行为进行了研究,结果表明,Zn对Ag-Cu合金的二次枝晶间距有细化作用;Ag-6Cu-xZn合金主要由α相(富Ag固溶体相)和少量的β相(富Cu和Zn固溶体相)组成,β相弥散分布于二次枝晶间;Zn的添加降低了合金及第二相的熔化温度,且 Zn 含量越高,合金熔化温度降低趋势越大,其凝固特征是一个典型的固溶体合金的非平衡凝固过程。
The as-cast microstructure, chemical phase and solidification behavior of Ag-6Cu-xZn (x=0, 1, 2) alloys were investigated. The results indicate that, the Zn in Ag-Cu alloy could refine the secondary dendrite arm spacing, but its refining effect is limited. The Ag-Cu-Zn alloy is mainly composed ofα phase (silver-rich phase) and littleβ phase ((copper, zinc)-rich phase).βphases are dispersively distributed in secondary dendrite, they will help to improve the abrasion resistance properties of materials. Adding Zn can reduce the melting temperature of the alloy and the second phase, the higher content of Zn, the greater tendency to reduce the melting temperature of the alloy, the solidification feature of Ag-Cu-Zn alloy is a typical of non-equilibrium solidification of Solid Solution.
参考文献
[1] | 于朝清,徐孝德,兰慧,赵华君,于丽琼.微电机用新型换向器材料[J].电工材料,2002(04):25-30,40. |
[2] | 陈亮维,罗锡明,谢明,周世平.银基二氧化铈和银基氧化铝合金的研究[J].稀有金属与硬质合金,2009(01):1-4. |
[3] | 陈永泰,王松,谢明,程勇,柳青,张吉明,杨有才.银基滑动电接触材料的研究进展[J].贵金属,2015(01):68-74. |
[4] | 卢绍平,杨红梅,杨富陶,俞建树,柳青,王健.Zn对AgCuNi4-0.5合金性能的影响[J].贵金属,2013(01):21-24. |
[5] | 刘勇,倪泽胜.微电机换向器用Ag-Cu-Cd材料的研究[J].电工材料,2001(04):13-16. |
[6] | 王健;周世平;杨富陶 等.微量Sn、Ce对AgCu合金的显微组织结构与力学性能影响[J].稀有金属,2007,31(z1):21-23. |
[7] | 章应,徐永红,廖国君,于朝清.微电机用环保复合金属材料现状及发展趋势[J].电工材料,2008(03):33-37. |
[8] | 杨青青,熊惟皓,沈丁杰,杨珍,王荣辉.Zn含量对Ag925CuZn合金显微组织和硬度的影响[J].稀有金属材料与工程,2008(06):947-951. |
[9] | 汤有正,向雄志,白晓军,牛飞.锌对925银抗变色性能的影响[J].稀有金属材料与工程,2012(05):929-931. |
[10] | 韩青有;胡汉起.多元合金中溶质浓度对二次枝晶臂间距的影响[J].北京钢铁学院学报,1985(1):1-11. |
[11] | 郑子樵.材料科学基础[M].长沙:中南大学出版社,2005 |
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