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本文基于负离子配位多面体生长基元模型,分析确定了两种晶型锑白的不同结构基元:SbO配位四面体与SbO3+3E星状四面体;详细探讨了水解法制锑白时水解介质等条件对其晶型结构影响的机理,得到了水解法制锑白时控制晶型结构的规律.

The different growth unites of two polymorph antimony white were analyzed and determined according to the theoretical model of growth units with coordination polyhedron structure of anion, and the chajnge characteristic of the polymorph structure of antimony white prepared by hydrolysis was discussed in detail, and the polymorph control mechanism of antimony white powders prepared by hydrolysis was revealed.

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