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概述了介孔材料的功能化方法,包括掺杂金属、引入无机物和接枝有机官能团等.重点介绍了材料改性后在水处理中的吸附与催化应用,包括吸附水中铜、铅、铬、砷等重金属离子,去除医药废水及水源水中的药物和内分泌干扰物以及胺类、酚类等有毒有害有机物,处理染料废水,催化降解水中挥发性有机物和工业废水中的多种染料分子等.最后展望了介孔材料未来的研究趋势与应用前景.

参考文献

[1] 胡轶凡 .新型硅介孔材料的合成与表征[D].上海:复旦大学,2011.
[2] 孙永军.介孔材料的研究进展[J].山东建筑大学学报,2009(04):362-368.
[3] 王冲,罗劭娟,任艳群,奚红霞.硅基介孔材料研究进展[J].化学工程,2011(12):21-25.
[4] Chuah G K;Hu X;Zhan P et al.Catalysts from MCM-41:Framework modification,pore size engineering,and organic-inorganic hybrid materials[J].Journal of Molecular Catalysis A:Chemical,2002,181(1-2):25.
[5] Caixia Lv;Yi Zhou;Hong Li;Mingming Dang;Changchun Guo;Yancong Ou;Bin Xiao .Synthesis and characterisation of Gd~(3+)-doped mesoporous TiO_2 materials[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2011(11):5104-5108.
[6] ZHAN Wangcheng,GUO Yanglong,WANG Yanqin,GUO Yun,LU Guanzhong.Synthesis of lathanum or La-B doped KIT-6 mesoporous materials and their application in the catalytic oxidation of styrene[J].稀土学报(英文版),2010(03):369-375.
[7] Li M;Hui K N;Hui K S et al.Influence of modification method and transition metal type on the physicochemical properties of MCM-41 catalysts and their performances in the catalytic ozonation of toluene[J].Applied Catalysis B:Environmental,2011,107(3-4):245.
[8] ZHAN Wangcheng,LU Guanzhong,GUO Yanglong,GUO Yun,WANG Yunsong.Synthesis of Ln-doped MCM-41 mesoporous materials and their catalytic performance in oxidation of styrene[J].稀土学报(英文版),2008(01):59-65.
[9] Jianda Zhang,Zhemin Shen,Wenpo Shan,Ziyan Chen,Zhijian Mei,Yangming Lei,Wenhua Wang.Adsorption behavior of phosphate on Lanthanum(Ⅲ) doped mesoporous silicates material[J].环境科学学报(英文版),2010(04):507-511.
[10] Cyrus Zamani;Olga Casals;Teresa Andreu;Joan Ramon Morante;Albert Romano-Rodriguez .Detection of amines with chromium-doped WO_3mesoporous material[J].Sensors and Actuators, B. Chemical,2009(2):557-562.
[11] Lang J;Yan X;Liu W et al.Influence of nitric acid modification of ordered mesoporous carbon materials on their capacitive performances in different aqueous electrolytes[J].Journal of Power Sources,2012,204:220.
[12] Jun-Wei Lang;Xing-Bin Yan;Xiao-Yan Yuan;Jie Yang;Qun-Ji Xue .Study on the electrochemical properties of cubic ordered mesoporous carbon for supercapacitors[J].JOURNAL OF POWER SOURCES,2011(23):10472-10478.
[13] 韩梅,陈静,王锦堂,孙蕊.MCM-41中孔分子筛的改性及其应用[J].化工时刊,2006(06):63-66.
[14] Kanda Y;Kobayashi T;Uemichi Y;Namba S;Sugioka M .Effect of aluminum modification on catalytic performance of Pt supported on MCM-41 for thiophene hydrodesulfurization[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):111-118.
[15] Savidha Ramachandran;Jang-Hoon Ha;Do Kyung Kim .Hydrogen storage characteristics of metal oxide doped Al-MCM-41 mesoporous materials[J].Catalysis Communications,2007(12):1934-1938.
[16] Shao G;Wang F;Ren T et al.Hierarchical mesoporous phosphorus and nitrogen doped titania materials:Synthesis,characterization and visible-light photocatalytic activity[J].Applied Catalysis B:Environmental,2009,92(1-2):61.
[17] Machida M;Fotoohi B;Amamo Y et al.Cadmium(Ⅱ) adsorption using functional mesoporous silica and activated carbon[J].Journal of Hazardous Materials,2012,221-222:220.
[18] Trindade, F.J.;Rey, J.F.Q.;Brochsztain, S..Modification of molecular sieves MCM-41 and SBA-15 with covalently grafted pyromellitimide and 1,4,5,8-naphthalenediimide[J].Journal of Colloid and Interface Science,2012:34-40.
[19] Horcajada P;Ramila A;Gerard F;Vallet-Regi M .Influence of superficial organic modification of MCM-41 matrices on drug delivery rate[J].Solid state sciences,2006(10):1243-1249.
[20] Lin Xuanhao;Khuan Gaik .Base-functionalized MCM-41 as catalysts for the synthesis of monoglycerides[J].Journal of molecular catalysis, A. Chemical,1999(23):287-294.
[21] Yasmin, T;Muller, K .Synthesis and surface modification of mesoporous mcm-41 silica materials[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2010(20):3362-3374.
[22] 吴张雄 .新型碳基有序介孔材料的合成、功能化及性质与应用[D].复旦大学,2011.
[23] Chandra D;Das S K;Bhaumik A .A fluorophore grafted 2D-hexagonal mesoporous organosilica:Excellent ion-exchanger for the removal of heavy metal ions from wastewater[J].Microporous and Mesoporous Materials,2010,128(01):34.
[24] Guoliang Li;Zongshan Zhao;Jiyan Liu;Guibinjiang .Effective heavy metal removal from aqueous systems by thiol functionalized magnetic mesoporous silica[J].Journal of hazardous materials,2011(1):277-283.
[25] Huang, J.;Ye, M.;Qu, Y.;Chu, L.;Chen, R.;He, Q.;Xu, D..Pb (II) removal from aqueous media by EDTA-modified mesoporous silica SBA-15[J].Journal of Colloid and Interface Science,2012:137-146.
[26] Pillewan P et al.Removal of As(Ⅲ) and As(Ⅴ) from water by copper oxide incorporated mesoporous alumina[J].Journal of Hazardous Materials,2011,186(01):367.
[27] Wang P;Lo I M C .Synthesis of mesoporous magnetic γ-Fe2 O3 and its application to Cr(Ⅵ) removal from contaminated water[J].Water Research,2009,43(15):3727.
[28] Dou B et al.Adsorption performance of VOCs in ordered mesoporous silicas with different pore structures and surface chemistry[J].Journal of Hazardous Materials,2011,186(2-3):1615.
[29] Kim Y;Lee B;Choo K et al.Selective adsorption of bisphenol A by organic-inorganic hybrid mesoporous silicas[J].Microporous and Mesoporous Materials,2011,138(1-3):184.
[30] Sindia M. Rivera-Jimenez;Sandra Mendez-Gonzalez;Arturo Hernandez-Maldonado .Metal (M = Co~(2+), Ni~(2+), and Cu~(2+)) grafted mesoporous SBA-15: Effect of transition metal incorporation and pH conditions on the adsorption of Naproxen from water[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2010(3):470-479.
[31] Mansoor Anbia;Samira Salehi .Removal of acid dyes from aqueous media by adsorption onto amino-functionalized nanoporous silica SBA-3[J].Dyes and Pigments,2012(1):1-9.
[32] Paul, M.;Pal, N.;Bhaumik, A. .Selective adsorption and release of cationic organic dye molecules on mesoporous borosilicates[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2012(6):1461-1468.
[33] Jeong E et al.Removal of Cu(Ⅱ) from water by tetrakis (4 carboxyphenyl) porphyrin-functionalized mesoporous silica[J].Journal of Hazardous Materials,2011,185(2-3):1311.
[34] Zhang LX;Yu CC;Zhao WR;Hua ZL;Chen HR;Li L;Shi JL .Preparation of multi-amine-grafted mesoporous silicas and their application to heavy metal ions adsorption[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2007(44/46):4055-4061.
[35] Wang Y;Huang S;Kang S et al.Low-cost route for synthesis of mesoporous silica materials with high silanol groups and their application for Cu(Ⅱ) removal[J].Materials Chemistry and Physics,2012,132(2-3):1053.
[36] Hernández-Morales V;Nava R;Acosta-Silva Y J et al.Adsorption of lead (Ⅱ) on SBA-15 mesoporous molecular sieve functionalized with-NH2 groups[J].Microporous and Mesoporous Materials,2012,160:133.
[37] Yantasee W;Fryxell G E;Addleman R S et al.Selective removal of lanthanides from natural waters,acidic streams and dialysate[J].Journal of Hazardous Materials,2009,168(2-3):1233.
[38] Patra A K;Dutta A;Bhaumik A .Self-assembled mesoporous γ-Al2O3 spherical nanoparticles and their efficiency for the removal of arsenic from water[J].Journal of Hazardous Materials,2012,201-202:170.
[39] S.K. Swain;Tanushree Patnaik;V.K. Singh .Kinetics, equilibrium and thermodynamic aspects of removal of fluoride from drinking water using meso-structured zirconium phosphate[J].Chemical engineering journal,2011(3):1218-1226.
[40] The effect of surface modification on heavy metal ion removal from water by carbon nanoporous adsorbent[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(5):1347.
[41] Guo L L;Li J T;Zhang L X et al.A facile route to synthesize magnetic particles within hollow mesoporous spheres and their performance as separable Hg2+ adsorbents[J].Journal of Materials Chemistry,2008,23(18):2733.
[42] Pires J;Pinto M;Estella J;Echeverria JC .Characterization of the hydrophobicity of mesoporous silicas and clays with silica pillars by water adsorption and DRIFT[J].Journal of Colloid and Interface Science,2008(1):206-213.
[43] Bui T X et al.Organically functionalized mesoporous SBA15 as sorbents for removal of selected pharmaceuticals from water[J].Journal of Hazardous Materials,2011,193:156.
[44] Wang, G;Otuonye, AN;Blair, EA;Denton, K;Tao, ZM;Asefa, T .Functionalized mesoporous materials for adsorption and release of different drug molecules: A comparative study[J].Journal of Solid State Chemistry,2009(7):1649-1660.
[45] Wu Z;Meng Y;Zhao D .Nanocasting fabrication of ordered mesoporous phenol-formaldehyde resins with various structures and their adsorption performances for basic organic compounds[J].Microporous and Mesoporous Materials,2010,128(01):165.
[46] Removal Of Naphthalene From Petrochemical Wastewater Streams Using Carbon Nanoporous Adsorbent[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(9):5041-5047.
[47] Mansoor Anbia;Arezoo Ghaffari .Adsorption of phenolic compounds from aqueous solutions using carbon nanoporous adsorbent coated with polymer[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(23):9305-9310.
[48] Forgacs E et al.Removal of synthetic dyes from wa-stewaters:A review[J].Environment International,2004,30(07):953.
[49] Gupta, VK;Suhas .Application of low-cost adsorbents for dye removal - A review[J].Journal of Environmental Management,2009(8):2313-2342.
[50] Rai HS;Bhattacharyya MS;Singh J;Bansal TK;Vats P;Banerjee UC .Removal of dyes from the effluent of textile and dyestuff manufacturing industry: A review of emerging techniques with reference to biological treatment[J].Critical reviews in environmental science and technology,2005(3):219-238.
[51] Renuka N K;Shijina A V;Praveen A K .Mesoporous γ-alumina nanoparticles:Synthesis,characterization and dye removal efficiency[J].Materials Letters,2012,82:42.
[52] Tian Y;Wang X;Pan Y .Simple synthesis of Ni-containing ordered mesoporous carbons and their adsorption/desorption of methylene orange[J].Journal of Hazardous Materials,2012,213-214:361.
[53] Chichao Yu;Xiaoping Dong;Limin Guo .Template-Free Preparation of Mesoporous Fe2O3 and Its Application as Absorbents[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(35):13378-13382.
[54] Leda Maria Saragiotto Colpini;Helton Jose Alves;Onelia Aparecida Andreo dos Santos .Discoloration and degradation of textile dye aqueous solutions with titanium oxide catalysts obtained by the sol-gel method[J].Dyes and Pigments,2008(2):525-529.
[55] Yanhui Ao;Jingjing Xu;Degang Fu;Chunwei Yuan .A simple method to prepare N-doped titania hollow spheres with high photocatalytic activity under visible light[J].Journal of hazardous materials,2009(1/3):1057-1062.
[56] Ghazzal M N;Kebaili H;Joseph M et al.Photocatalytic degradation of Rhodamine 6G on mesoporous titania films:Combined effect of texture and dye aggregation forms[J].Applied Catalysis B:Environmental,2012,115-116:276.
[57] Dwivedi C;Raje N;Nuwad J et al.Synthesis and characterization of mesoporous titania microspheres and their appli cations[J].Chemical Engineering Journal,2012,193-194:178.
[58] Arconada N;Castro Y;Durán A et al.Photocatalytic oxidation of methyl ethyl ketones over sol-gel mesoporous and meso-structured TiO2 films obtained by EISA method[J].Applied Catalysis B:Environmental,2011,107(1-2):52.
[59] Ahmed M A .Synthesis and structural features of mesoporous NiO/TiO2 nanocomposites prepared by sol-gel method for photodegradation of methylene blue dye[J].Journal of Photochemistry and Photobiology A:Chemistry,2012,238:63.
[60] Ma Y;Xing M;Zhang J et al.Synthesis of well ordered mesoporous Yb,N co-doped TiO2 with superior visible photocatalytic activity[J].Microporous and Mesoporous Materials,2012,156:145.
[61] Boppana, V.B.R.;Lobo, R.F. .Photocatalytic degradation of organic molecules on mesoporous visible-light-active Sn(II)-doped titania[J].Journal of Catalysis,2011(1):156-168.
[62] Blanco M;Pizzio L .Influence of the thermal treatment on the physicochemical properties and photocatalytic degradation of 4-chlorophenol in aqueous solutions with tungstophosphoric acid-modified mesoporous titania[J].Applied Catalysis A:General,2011,405(1-2):69.
[63] SHI Zhongliang,YANG Xingman,YAO Shuhua.Photocatalytic activity of cerium-doped mesoporous TiO2 coated Fe3O4magnetic composite under UV and visible light[J].稀土学报(英文版),2012(04):355-360.
[64] Lin S;Su G;Zheng M et al.Synthesis of flower-like Co3 O4-CeO2 composite oxide and its application to catalytic degradation of 1,2,4-trichlorobenzene[J].Applied Catalysis B:Environmental,2012,123-124:440.
[65] Preparation of ordered mesoporous Ag/WO_3 and its highly efficient degradation of acetaldehyde under visible-light irradiation[J].Journal of hazardous materials,2010(1/3):427.
[66] Xu J et al.Photocatalytic degradation of tetrabromobisphenol A by mesoporous BiOBr:Efficacy,products and pathway[J].Applied Catalysis B:Environmental,2011,107(3-4):355.
[67] Muruganandham M;Amutha R;Repo E et al.Controlled mesoporous self-assembly of ZnS microsphere for photocatalytic degradation of methyl orange dye[J].Journal of Photochemistry and Photobiology A:Chemistry,2010,216(2-3):133.
[68] Liying Shi;Sheng Chu;Fei Kong .Tailoring the nano-channel of ZrO_2/SBA-15 mesoporous materials for efficiently trapping and degradation volatile nitrosamines[J].Solid state sciences,2011(12):2105-2112.
[69] Yu Zhou;Fang Na Gu;Ling Gao .3D net-linked mesoporous silica monolith: New environmental adsorbent and catalyst[J].Catalysis Today,2011(1):39-46.
[70] Qiu X et al.Degradation of decabromodiphenyl ether by nano zero-valent iron immobilized in mesoporous silica microspheres[J].Journal of Hazardous Materials,2011,193:70.
[71] Self-assembled mesoporous carbon films for platinum metal catalyst loading[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(14):p.3604.
[72] Yamamoto T;Kim S;Chaichanawong J et al.Removal of aqueous organic pollutants by adsorption-catalytic process using mesoporous carbon beads loaded with metal oxides[J].Applied Catalysis B:Environmental,2009,88(3-4):455.
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