采用传统固相反应法制备了0.94(Na0.5 Bi0.) TiO3-0.06BaTiO3-3wt% Bi2 O3-xwt% Nd2O3(x=0,1.5)陶瓷.研究了Bi3+和Nd3+掺杂对0.94 (Na0.5 Bi05)TiO3-0.06BaTiO3陶瓷结构和电学性能的影响.结果表明,Bi2O3和Nd2O3掺杂不影响0.94(Na0.5 Bi0.5) TiO3-0.06BaTiO3的钙钛矿结构.3wt% Bi2O3添加使得铁电陶瓷0.94(Na0.5Bi05) TiO3-0.06BaTiO3转变为反铁电陶瓷.反铁电陶瓷0.94(Na0.5Bi0.5)TiO3-0.06BaTiO3-3wt% Bi2O3具有更高的相转变温度Tm(~320℃).Nd2O3添加不改变0.94(Na0.5 Bi0.5) TiO3-0.06BaTiO3-3wt% Bi2O3陶瓷的反铁电态,但增强了陶瓷的介电性能和弛豫性能.
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