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采用“熔融挤出-冷拉伸-微注成型”方法成功制备了可降解型高分子——聚丁二酸丁二醇酯(PBS)/聚乳酸(PLA)的原位成纤复合材料,其中PBS为基体连续相而PLA为微纤增强相;并从组分黏度比、组分含量比以及拉伸形变比三方面分析讨论了微纤化结构的形成条件.扫描电子显微镜观察结果表明,所采用的可降解型高分子原料的黏度比并不在最适宜成纤的范围内,但提高拉伸比以及高的PLA含量都可以增加PLA微纤的数量和长径比.研究发现PLA相部分形成微纤化结构后,由于自身力学性能的提高并且增加了两相间的界面作用,对PBS/PLA复合材料体系有显著增强作用.拉伸强度与拉伸模量分别比纯PBS提高了55%和140%,优于文献报道的几种天然纤维对PBS的增强效果.

参考文献

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